433063
Sodium methanesulfinate
technical grade, 85%
Sinônimo(s):
Methanesulfinic acid sodium salt
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About This Item
Produtos recomendados
grau
technical grade
Nível de qualidade
Ensaio
85%
pf
222-226 °C (dec.) (lit.)
grupo funcional
sulfinic acid
cadeia de caracteres SMILES
[Na+].CS([O-])=O
InChI
1S/CH4O2S.Na/c1-4(2)3;/h1H3,(H,2,3);/q;+1/p-1
chave InChI
LYPGDCWPTHTUDO-UHFFFAOYSA-M
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Descrição geral
Sodium methanesulfinate is an aliphatic sodium sulfinate. Conjugate addition of sodium methanesulfinate to vinyl heterocycles has been described. Cross-coupling reaction between aryl boronic acid and sodium methanesulfinate has been studied. Its stock solution was prepared from methanesulfonic acid by adding one equivalent of sodium hydroxide and diluting it to 4M.
Palavra indicadora
Warning
Frases de perigo
Classificações de perigo
Acute Tox. 4 Oral
Código de classe de armazenamento
11 - Combustible Solids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
Not applicable
Ponto de fulgor (°C)
Not applicable
Equipamento de proteção individual
dust mask type N95 (US), Eyeshields, Gloves
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Metal-Free Direct Construction of Sulfonamides via Iodine-Mediated Coupling Reaction of Sodium Sulfinates and Amines at Room Temperature.
Advanced Synthesis & Catalysis, 357(5), 987-992 (2015)
Free radical research communications, 8(2), 101-106 (1990-01-01)
Iron bound to certain chelators is known to promote the conversion of superoxide radicals (O2-) to hydroxyl radicals (HO.) by the superoxide-driven Fenton reaction. The production of HO. by various iron chelates was studied using the reaction of dimethyl sulfoxide
Archives of biochemistry and biophysics, 278(2), 478-481 (1990-05-01)
This investigation was conducted to validate the use of dimethyl sulfoxide (DMSO) as a quantitative molecular probe for the generation of hydroxyl radicals (HO.) in aqueous systems. Reaction of HO. with DMSO produces methane sulfinic acid as a primary product
Free radical biology & medicine, 9(1), 67-77 (1990-01-01)
To quantitate the formation of hydroxyl radicals (HO.) in ischemia and reoxygenation, dimethyl sulfoxide (DMSO) was added to "trap" evolving HO. in normal, in ischemic, and in ischemic and reoxygenated rat kidney slices, incubated in short-term organ culture in vitro.
Journal of chromatography, 630(1-2), 187-193 (1993-02-05)
For the determination of hydroxyl radicals, dimethyl sulphoxide was used as a molecular probe and the methanesulphinic acid produced was determined by high-performance liquid chromatography of its Fast Yellow GC salt derivative. The results for hydroxyl radicals formed using the
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