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431648

Sigma-Aldrich

Sodium sulfide nonahydrate

≥99.99% trace metals basis

Sinônimo(s):

Disodium sulfide nonahydrate, Sodium sulfide enneahydrate

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About This Item

Fórmula linear:
Na2S·9H2O
Número CAS:
Peso molecular:
240.18
Número CE:
Número MDL:
Código UNSPSC:
12352300
ID de substância PubChem:
NACRES:
NA.23
Ensaio:
≥99.99% trace metals basis
Formulário:
crystals and lumps

Nível de qualidade

Ensaio

≥99.99% trace metals basis

Formulário

crystals and lumps

adequação da reação

reagent type: catalyst
core: sodium

Impurezas

<100 ppm total metallic impurities

traços de ânion

SO32- and S2O32-: ≤0.1%

traços de cátion

Fe:, passes test
NH4+: ≤0.005%

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

O.O.O.O.O.O.O.O.O.[Na]S[Na]

InChI

1S/2Na.9H2O.S/h;;9*1H2;

chave InChI

UIINQVYGFKNSPA-UHFFFAOYSA-N

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Descrição geral

Sodium sulfide nonahydrate is a chemical compound with the formula Na2S-H2O. It is a white to yellow hygroscopic solid that is highly soluble in water and has a strong, unpleasant odor. Sodium sulfide nonahydrate is typically made by dissolving elemental sulfur in a solution of sodium hydroxide, which leads to the formation of sodium sulfide. The nonahydrate form of the compound is formed by adding excess water to the solution, which leads to the formation of a crystalline solid with nine molecules of water per molecule of sodium sulfide. Sodium sulfide nonahydrate is often used as a reducing agent in chemical reactions as well as a flotation agent in the mining industry. It is also used in the production of dyes, pigments, and other chemicals.

Aplicação

Sodium sulfide nonahydrate (Na2S.9H2O) can be reacted with α,ω-dibromo and/or α,ω-dichloroalkane for the synthesis of polyalkylene sulfide. It can be used as a reducing agent for the removal of nitrogen oxide from the exhaust gas. Na2S.9H2O can also be used as an inexpensive sulfur source for the synthesis of heterocyclic thiochromes.

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Código de classe de armazenamento

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Absorption-reduction technique assisted by ozone injection and sodium sulfide for NOx removal from exhaust gas
Mok YS
Chemical Engineering Journal, 118(1-2), 63-67 (2006)
The synthesis of polymeric sulfides by reaction of dihaloalkanes with sodium sulfide
Smith K, et al.
Journal of Sulfur Chemistry, 32(6), 521-531 (2011)
The reaction products of sulfide and S-nitrosoglutathione are potent vasorelaxants.
Berenyiova A, et al.
Nitric Oxide, 46, 123-130 (2015)
Veinot, J.G.C. et al.
Chemistry of Materials, 9, 2117-2117 (1997)
Renfa Liu et al.
Theranostics, 5(10), 1144-1153 (2015-08-19)
The integration of diagnostic and therapeutic functionalities into one nanoplatform shows great promise in cancer therapy. In this research, manganese (II) chelate functionalized copper sulfide nanoparticles were successfully prepared using a facile hydrothermal method. The obtained ultrasmall nanoparticles exhibit excellent

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