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Sigma-Aldrich

1,1′-Azobis(cyclohexanecarbonitrile)

98%

Sinônimo(s):

1,1′-Azobis(cyanocyclohexane), ACHN

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About This Item

Fórmula linear:
NCC6H10N=NC6H10CN
Número CAS:
2094-98-6
Peso molecular:
244.34
Beilstein:
960744
Número CE:
218-254-8
Número MDL:
MFCD00046334
Código UNSPSC:
12162002
ID de substância PubChem:
24863728
NACRES:
NA.23

Nível de qualidade

200

Ensaio

98%

Formulário

solid

pf

114-118 °C (lit.)

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

N#CC1(CCCCC1)\N=N\C2(CCCCC2)C#N

InChI

1S/C14H20N4/c15-11-13(7-3-1-4-8-13)17-18-14(12-16)9-5-2-6-10-14/h1-10H2/b18-17+

chave InChI

KYIKRXIYLAGAKQ-ISLYRVAYSA-N

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Descrição geral

1,1′-Azobis(cyclohexanecarbonitrile) (AHCN) is a thermally stable initiator that can be used in free-radical polymerization. It is soluble in a variety of solvents such as methanol, dimethylformamide (DMF), etc.

Aplicação

A more efficient radical initiator than AIBN has been employed to initiate primary radical reactions.

Pictogramas

FlameExclamation mark
GHS02,GHS07

Palavra indicadora

Danger

Frases de perigo

H242,H315,H319,H335

Classificações de perigo

Eye Irrit. 2 - Self-react. D - Skin Irrit. 2 - STOT SE 3

Órgãos-alvo

Respiratory system

Código de classe de armazenamento

5.2 - Organic peroxides and self-reacting hazardous materials

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análise (COA)

Lot/Batch Number
MKCQ0071
MKCH5807
MKCJ6952
MKCJ0116
MKBH4387V

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1, 11 AZOBIS (CYCLOHEXANECARBONITRILE) INITIATED COPOLYMERIZATION OF ACRYLONITRILE COPOLYMERS AND THEIR CHARACTERIZATION
Sridevi S, et al.
Chem, 2(5), 61-61 (2009)
Youfeng Yue et al.
Nature communications, 9(1), 3234-3234 (2018-08-15)
Energy conversion of light into mechanical work is of fundamental interest in applications. In particular, diligent molecular design on nanoscale, in order to achieve efficient photomechanical effects on macroscopic scale, has become one of the most interesting study topics. Here
The Journal of Organic Chemistry, 52, 2958-2958 (1987)
Heyu Li et al.
Colloids and surfaces. B, Biointerfaces, 159, 277-283 (2017-08-13)
In this study, the thermosensitive polymer poly(di(ethylene glycol) methyl ether methacrylate) (PDEGMA) was synthesized and electrospun into fibers by blending with ethyl cellulose (EC). Fibers were additionally prepared loaded with ketoprofen (KET) as a model drug. Smooth cylindrical fibers could
Supitchaya Iamsaard et al.
Macromolecular rapid communications, 39(12), e1800071-e1800071 (2018-05-12)
Previous couplings of corrosion inhibitors to redox-responsive polymers via covalent bonding suffer from several drawbacks. It is presented here novel redox-responsive polymer-corrosion inhibitor conjugates that contain self-immolative linkers in their side chains. Very fast redox-induced release of tryptamine, a drug
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