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278505

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Sulfuryl chloride solution

1.0 M in methylene chloride

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About This Item

Fórmula linear:
SO2Cl2
Número CAS:
Peso molecular:
134.97
Número MDL:
Código UNSPSC:
12352300
ID de substância PubChem:
NACRES:
NA.23
Formulário:
liquid

Formulário

liquid

Nível de qualidade

concentração

1.0 M in methylene chloride

densidade

1.352 g/mL at 25 °C

cadeia de caracteres SMILES

ClS(Cl)(=O)=O

InChI

1S/Cl2O2S/c1-5(2,3)4

chave InChI

YBBRCQOCSYXUOC-UHFFFAOYSA-N

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Aplicação


  • Palladium-Catalyzed Synthesis of Ammonium Sulfinates from Aryl Halides and a Sulfur Dioxide Surrogate: A Gas-and Reductant-Free Process: This study elaborates on using sulfuryl chloride for oxidative chlorination leading to sulfonyl chloride formation, which is important for synthetic organic chemistry (Emmett et al., 2014).

  • Combining Organometallic Reagents, the Sulfur Dioxide Surrogate DABSO, and Amines: A One‐Pot Preparation of Sulfonamides, Amenable to Array Synthesis: This research discusses an innovative one-pot method for preparing sulfonamides using sulfuryl chloride, highlighting its utility in streamlining complex syntheses (Deeming et al., 2015).

  • Interfacial polymerization: from chemistry to functional materials: The article illustrates the use of sulfuryl chloride in interfacial polymerization, a key technique for developing advanced materials with tailored properties (Zhang et al., 2020).

Palavra indicadora

Danger

Frases de perigo

Classificações de perigo

Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1C - STOT SE 3

Órgãos-alvo

Central nervous system

Perigos de suplementos

Código de classe de armazenamento

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de risco de água (WGK)

WGK 2

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Iron-catalyzed desulfinylative C-C cross-coupling reactions of sulfonyl chlorides with grignard reagents.
Chandra M Rao Volla et al.
Angewandte Chemie (International ed. in English), 47(7), 1305-1307 (2008-01-05)
Michael Harmata et al.
The Journal of organic chemistry, 72(2), 683-685 (2007-01-16)
Sulfinamides were synthesized from sulfonyl chlorides using a procedure involving in situ reduction of sulfonyl chlorides. The reaction is broad in scope and easy to perform.
Polystyrene sulfonyl chloride: a highly orthogonal linker resin for the synthesis of nitrogen-containing heterocycles.
Matthias Mentel et al.
Angewandte Chemie (International ed. in English), 48(32), 5841-5844 (2009-07-08)
Vlad Martin-Diaconescu et al.
Inorganic chemistry, 48(3), 1038-1044 (2009-01-10)
The electronic structure of organic sulfonyl compounds of the form RSO(2)G (G = -Cl, -OH, -CH(3)) is investigated to evaluate the effect of aryl R groups on photocleavage of the S-G bond. Sulfur K-edge X-ray absorption spectroscopy (XAS) provides a
James A H Inkster et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(35), 11079-11087 (2012-07-19)
Nucleophilic incorporation of [(18)F]F(-) under aqueous conditions holds several advantages in radiopharmaceutical development, especially with the advent of complex biological pharmacophores. Sulfonyl fluorides can be prepared in water at room temperature, yet they have not been assayed as a potential

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