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Key Documents

235695

Sigma-Aldrich

Octamethylcyclotetrasiloxane

98%

Sinônimo(s):

2,2,4,4,6,6,8,8-Octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane, octamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane

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About This Item

Fórmula linear:
[-Si(CH3)2O-]4
Número CAS:
Peso molecular:
296.62
Beilstein:
1787074
Número CE:
Número MDL:
Código UNSPSC:
12352103
ID de substância PubChem:
NACRES:
NA.23

densidade de vapor

1 (vs air)

Nível de qualidade

Ensaio

98%

forma

liquid

índice de refração

n20/D 1.396 (lit.)

pb

175-176 °C (lit.)

pf

17-18 °C (lit.)

densidade

0.956 g/mL at 25 °C (lit.)

cadeia de caracteres SMILES

C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1

InChI

1S/C8H24O4Si4/c1-13(2)9-14(3,4)11-16(7,8)12-15(5,6)10-13/h1-8H3

chave InChI

HMMGMWAXVFQUOA-UHFFFAOYSA-N

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Descrição geral

Octamethylcyclotetrasiloxane (D4) is a volatile methylsiloxane (VMS) with a relatively low molecular weight. This silicone fluid has a silicon-oxygen bond in a cyclic arrangement and methyl groups are attached to the silicon atom. D4 can be used in the manufacture of silicone based polymers for use in medical devices and personal care products.

Aplicação

D4 can be polymerized through ring opening mechanism with a rare earth solid super acid as a catalyst for potential usage in the synthesis of vinyl coated polydimethylsiloxane (PDMS). It may also be used as a probe liquid for nuclear magnetic resonance cryoporometry (NMRC) to analyze the pore size distribution (PSD) of oil-bearing tight sandstone. Chemical vapor deposition (CVD) of D4 may be utilized for the preparation of siloxane based thin films.

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3 - Repr. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

123.8 °F - closed cup

Ponto de fulgor (°C)

51 °C - closed cup

Equipamento de proteção individual

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Certificados de análise (COA)

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Photocatalytic oxidation of octamethylcyclotetrasiloxane (D4): Towards a better understanding of the impact of volatile methyl siloxanes on photocatalytic systems.
Lamaa L, et al.
Applied Catalysis. B, Environmental, 156, 438-446 (2014)
Synthesis of vinyl end-capped polydimethylsiloxane by ring opening polymerization of octamethylcyclotetrasiloxane (D4) catalyzed by rare earth solid super acid SO42-/TiO2/Ln3+.
Yang X, et al.
Polymer International, 63(2), 347-351 (2014)
Hot-filament chemical vapor deposition of organosilicon thin films from hexamethylcyclotrisiloxane and octamethylcyclotetrasiloxane.
Lewis HGP
Journal of the Electrochemical Society, 148(12), F212-F220 (2001)
Stephanie Watermann et al.
Metabolites, 11(1) (2021-01-13)
1H NMR spectroscopy, in combination with chemometric methods, was used to analyze the methanol/acetonitrile (1:1) extract of walnut (Juglans Regia L.) regarding the geographical origin of 128 authentic samples from different countries (France, Germany, China) and harvest years (2016-2019). Due
Applying octamethylcyclotetrasiloxane as a probe liquid for characterizing the pore size distribution of oil-bearing tight sandstones by nuclear magnetic resonance cryoporometry.
Liu Biao, et al.
Marine and Petroleum Geology, 88(2), 814-825 (2017)

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