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Sigma-Aldrich

1-Hexanethiol

95%

Sinônimo(s):

1-Mercaptohexane, Hexyl mercaptan, MCH, Mercaptan C6

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About This Item

Fórmula linear:
CH3(CH2)5SH
Número CAS:
111-31-9
Peso molecular:
118.24
Beilstein:
1731295
Número CE:
203-857-0
Número MDL:
MFCD00004909
Código UNSPSC:
12352103
ID de substância PubChem:
24854028
NACRES:
NA.23

Ensaio

95%

Formulário

liquid

índice de refração

n20/D 1.450

p.e.

150-154 °C (lit.)

pf

−81-−80 °C (lit.)

densidade

0.832 g/mL at 25 °C

cadeia de caracteres SMILES

CCCCCCS

InChI

1S/C6H14S/c1-2-3-4-5-6-7/h7H,2-6H2,1H3

chave InChI

PMBXCGGQNSVESQ-UHFFFAOYSA-N

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Descrição geral

1-Hexanethiol is an organothiol that forms a self-assembled monolayer (SAM) on a variety of nanoparticles. It consists of S head group, CH2 alkane chain, and CH3 terminal group.

Aplicação

1-Hexanethiol can be mixed with 4-mercaptophenol to functionalize gold nanoparticles (AuNPs) for use as chemi-resistive sensors. It can also form a protective coating against oxidative reactions and contaminating layers on copper surfaces. It can also be used as a thiol based ligand which finds potential application as a semiconducting material in thin film solar cells.
It is used to tune the electrical characteristics in networked carbon nanotube field-effect transistors. It is also used as a monolayer on copper surfaces to retard surface oxidation during exposure to the environment which can then be desorbed effectively with an annealing step in inert N2 to provide a clean Cu surface.

Pictogramas

FlameExclamation mark
GHS02,GHS07

Palavra indicadora

Warning

Frases de perigo

H226,H302

Classificações de perigo

Acute Tox. 4 Oral - Flam. Liq. 3

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

86.0 °F - closed cup

Ponto de fulgor (°C)

30 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
0000104549
STBJ1680
STBG3802V
STBC5623V
S76993

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Sigma-Aldrich

510467

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Sigma-Aldrich

705233

1-Decanethiol

M Chen et al.
The Journal of investigative dermatology, 108(1), 68-72 (1997-01-01)
Epidermolysis bullosa acquisita (EBA) is an acquired blistering skin disease characterized by the presence of IgG autoantibodies to type VII collagen. EBA autoantibodies recognize four major immunodominant epitopes localized within the amino-terminal, noncollagenous (NC1) domain. In this study, we developed
Tan, C. S.; Lim, D. F.; Singh, S. G.; Goulet, S. K.; Bergkvist, M.
Applied Physics Letters, 91, 192108-192108 (2007)
T Hashimoto et al.
The British journal of dermatology, 134(2), 336-339 (1996-02-01)
In this study we present a patient with the sublamina densa type of linear IgA bullous dermatosis (LABD), with IgA autoantibodies reactive with the 290-kDa type VII collagen (the epidermolysis bullosa acquisita (EBA) antigen) and with immunoblotting of normal human
Different ligand exchange solvents effect on the densification of CuIn0. 7Ga0. 3Se2 prepared using the heating-up method
Yang C and Hsiang H
Applied Surface Science, 426(2), 1148-1157 (2017)
N Yasaka et al.
Journal of dermatological science, 7(2), 136-141 (1994-04-01)
The cutaneous basement membrane zone (BMZ) is composed of a large number of molecular components. We have recently reported that one of the CD1b monoclonal antibodies (MoAb), NU-T2, reacts to the BMZ of the normal human skin, esophagus and stomach.
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