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226637

Sigma-Aldrich

Butyl nitrite

95%

Sinônimo(s):

n-Butyl nitrite

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About This Item

Fórmula linear:
CH3(CH2)3ONO
Número CAS:
544-16-1
Peso molecular:
103.12
Beilstein:
1701036
Número CE:
208-862-1
Número MDL:
MFCD00002058
Código UNSPSC:
12352100
ID de substância PubChem:
24853580
NACRES:
NA.22

pressão de vapor

760 mmHg ( 78 °C)

Nível de qualidade

100

Ensaio

95%

Formulário

liquid

índice de refração

n20/D 1.376 (lit.)

p.e.

78 °C (lit.)

solubilidade

alcohol: miscible(lit.)
diethyl ether: miscible(lit.)

densidade

0.882 g/mL at 25 °C (lit.)

grupo funcional

O-nitroso
nitroso

temperatura de armazenamento

2-8°C

cadeia de caracteres SMILES

CCCCON=O

InChI

1S/C4H9NO2/c1-2-3-4-7-5-6/h2-4H2,1H3

chave InChI

JQJPBYFTQAANLE-UHFFFAOYSA-N

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Descrição geral

The photodissociation dynamics of butyl nitrite was studied using time-resolved Fourier transform infrared (TR-FTIR) emission spectroscopy. The effects of butyl nitrite on methyl cobalamin and 5-methyl tetrahydrofolate were studied.

Pictogramas

FlameSkull and crossbones
GHS02,GHS06

Palavra indicadora

Danger

Frases de perigo

H225,H301,H330

Classificações de perigo

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

Código de classe de armazenamento

3 - Flammable liquids

Classe de risco de água (WGK)

WGK 1

Ponto de fulgor (°F)

8.6 °F - closed cup

Ponto de fulgor (°C)

-13 °C - closed cup

Equipamento de proteção individual

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análise (COA)

Lot/Batch Number
MKCQ5122
MKCN7719
MKCN5365
MKCM2877
MKCL4353

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G R Newell et al.
Pharmacotherapy, 4(5), 284-291 (1984-09-01)
Volatile nitrite in the form of amyl nitrite was used for 100 years for the treatment of angina pectoris. In spite of recognized toxicity, its use in this form was considered safe. During the 1960s prescriptions were not required for
J D Osterloh et al.
Journal of pharmaceutical sciences, 74(7), 780-782 (1985-07-01)
The uptake of butyl nitrite by rats (500 g, one rat/chamber) was determined over a 5-min exposure period. About 44% of the starting amount (771-3855 ppm) of n-butyl nitrite was consumed in 5 min. Three rats per exposure concentration were
Tsuyoshi Taniguchi et al.
Chemical communications (Cambridge, England), 49(22), 2198-2200 (2013-02-12)
A method for direct functionalization of three positions including an unactivated C-H bond of aliphatic alkenes using tert-butyl nitrite and molecular oxygen to give γ-lactols has been developed. The present reaction proceeds through a sequence of radical processes involving oxynitration
Dipankar Koley et al.
Organic letters, 11(18), 4172-4175 (2009-08-25)
tert-Butyl nitrite was identified as a safe and chemoselective nitrating agent that provides preferentially mononitro derivatives of phenolic substrates in the presence of potentially competitive functional groups. On the basis of our control experiments, we propose that the reaction proceeds
E Roth et al.
American journal of hematology, 20(2), 153-159 (1985-10-01)
The use of volatile butylnitrite in place of sodium nitrite for the in vitro production of methemoglobin was explored in studies of G6PD-deficient red cells and for measurements of the red cell methemoglobin reductase activity. It was found that butylnitrite
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