179752
Borane pyridine complex
~8 M BH3
Sinônimo(s):
NSC 10219, NSC 53324, Pyridine borane, Trihydro(pyridine)boron
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About This Item
Fórmula empírica (Notação de Hill):
C5H8BN
Número CAS:
Peso molecular:
92.93
Número MDL:
Código UNSPSC:
12352005
eCl@ss:
39151701
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
forma
liquid
Nível de qualidade
adequação da reação
reagent type: reductant
concentração
~8 M BH3
índice de refração
n20/D 1.532 (lit.)
pf
10-11 °C (lit.)
densidade
0.92 g/mL at 25 °C (lit.)
temperatura de armazenamento
2-8°C
cadeia de caracteres SMILES
[BH3-][n+]1ccccc1
InChI
1S/C5H8BN/c6-7-4-2-1-3-5-7/h1-5H,6H3
chave InChI
LPGWNCNRGQANGC-UHFFFAOYSA-N
Aplicação
Borane pyridine complex is commonly used as a reducing reagent for the reductive amination of aldehydes and ketones. It is the precursor to synthesize carbon-based material, BC4N. Along with iodine, it can be used as a reagent for hydroboration of alkenes and alkynes.
Used for:
Reducing agent for high performance liquid chromatography analysis of oligosaccharides
Modifier in decant oil affecting its carbonization to mesophase pitch
- Investigations of site energy distribution functions from Toth isotherm for adsorption of gases on heterogeneous surfaces
- Preparation of α−alkyl-β-hydroxy esters
- Regioselective immobilization of short oligonucleotides to acrylic copolymer gels
- Preparation of Igs conjugated with viral peptide epitopes
- Sintering of silicon carbide
Reducing agent for high performance liquid chromatography analysis of oligosaccharides
Modifier in decant oil affecting its carbonization to mesophase pitch
Atenção
May darken in storage.
Outras notas
may contain excess pyridine
Palavra indicadora
Danger
Frases de perigo
Declarações de precaução
Classificações de perigo
Acute Tox. 1 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2
Código de classe de armazenamento
3 - Flammable liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
69.8 °F
Ponto de fulgor (°C)
21 °C
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A novel carbon material derived from pyridine-borane.
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Advanced Materials, 3(11), 551-552 (1991)
T Miron et al.
Analytical biochemistry, 440(1), 12-14 (2013-05-28)
In this note, we describe a method devised to detect, by means of mass spectrometry (MS), tryptophan-containing peptides and proteins using pyridine-borane. This reagent selectively reduces tryptophan residues, converting them to 2,3-dihydro-tryptophan, thereby enabling quantitation of tryptophans.
Journal of the Chemical Society. Perkin Transactions 1, 717-717 (1984)
Jethro L Hemmann et al.
Proceedings of the National Academy of Sciences of the United States of America, 116(51), 25583-25590 (2019-11-30)
Methylotrophy, the ability of microorganisms to grow on reduced one-carbon substrates such as methane or methanol, is a feature of various bacterial species. The prevailing oxidation pathway depends on tetrahydromethanopterin (H4MPT) and methylofuran (MYFR), an analog of methanofuran from methanogenic
Hydroboration with pyridine borane at room temperature.
Clay, Julia M and Vedejs, Edwin
Journal of the American Chemical Society, 127(16), 5766-5767 (2005)
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