135194
Bromocyclohexane
98%
Sinônimo(s):
Cyclohexyl bromide
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About This Item
Fórmula empírica (Notação de Hill):
C6H11Br
Número CAS:
Peso molecular:
163.06
Beilstein:
1098373
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22
Produtos recomendados
Ensaio
98%
Formulário
liquid
índice de refração
n20/D 1.495 (lit.)
p.e.
166-167 °C (lit.)
solubilidade
H2O: insoluble
alcohol: soluble
densidade
1.324 g/mL at 25 °C (lit.)
grupo funcional
bromo
cadeia de caracteres SMILES
BrC1CCCCC1
InChI
1S/C6H11Br/c7-6-4-2-1-3-5-6/h6H,1-5H2
chave InChI
AQNQQHJNRPDOQV-UHFFFAOYSA-N
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Descrição geral
Axial conformer of bromocyclohexane forms inclusion complexes with 9,9′-bianthryl and exhibits a weak 1,3 diaxial Cl...H interaction. It participates in the alkylation reaction of of para-xylene in the presence of graphite as catalyst to yield hydrocarbon.
Aplicação
Bromocyclohexane has been used to study the ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane using vacuum ultraviolet mass-analyzed threshold ionization spectroscopy.
Frases de perigo
Declarações de precaução
Classificações de perigo
Aquatic Chronic 2
Código de classe de armazenamento
10 - Combustible liquids
Classe de risco de água (WGK)
WGK 3
Ponto de fulgor (°F)
145.4 °F - closed cup
Ponto de fulgor (°C)
63 °C - closed cup
Equipamento de proteção individual
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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Shinya Hirano et al.
Chemical communications (Cambridge, England), (29)(29), 3646-3648 (2005-07-20)
The axial conformers of chloro- and bromocyclohexane were isolated in a pure state as inclusion complexes with 9,9'-bianthryl, and a 1,3 diaxial Cl...H weak interaction was discovered by X-ray analysis of the axial conformer of chlorocyclohexane.
Alkylation on graphite in the absence of Lewis acids.
Sereda GA.
Tetrahedron Letters, 45(39), 7265-7267 (2004)
Songhee Han et al.
The journal of physical chemistry. A, 114(37), 10005-10010 (2010-08-27)
Ionization of equatorial and axial conformational isomers of the chair-bromocyclohexane is investigated with use of the vacuum ultraviolet mass-analyzed threshold ionization (MATI) spectroscopic technique. Two distinct ionization energies of 9.8308 ± 0.0025 and 9.8409 ± 0.0025 eV are determined for
Hanumantha Rao Vutukuri et al.
Angewandte Chemie (International ed. in English), 53(50), 13830-13834 (2014-11-05)
Particle shape is a critical parameter that plays an important role in self-assembly, for example, in designing targeted complex structures with desired properties. Over the last decades, an unprecedented range of monodisperse nanoparticle systems with control over the shape of
Marjolein N van der Linden et al.
Langmuir : the ACS journal of surfaces and colloids, 31(1), 65-75 (2014-12-24)
We studied suspensions of sterically stabilized poly(methyl methacrylate) (PMMA) particles in the solvent cyclohexyl bromide (CHB; εr = 7.92). We performed microelectrophoresis measurements on suspensions containing a single particle species and on binary mixtures, using confocal microscopy to measure the
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