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Documentos Principais

133221

Sigma-Aldrich

Bis(5-chloro-2-hydroxyphenyl)methane

95%

Sinônimo(s):

Dichlorophen, Dichlorophene

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About This Item

Fórmula linear:
CH2[C6H3(Cl)OH]2
Número CAS:
Peso molecular:
269.12
Beilstein:
1884514
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de substância PubChem:
NACRES:
NA.22

Nível de qualidade

Ensaio

95%

forma

powder

pf

168-172 °C (lit.)

solubilidade

95% ethanol: soluble 1g/g
methanol: soluble
petroleum ether: soluble
toluene: very slightly soluble
water: insoluble

grupo funcional

chloro

cadeia de caracteres SMILES

Oc1ccc(Cl)cc1Cc2cc(Cl)ccc2O

InChI

1S/C13H10Cl2O2/c14-10-1-3-12(16)8(6-10)5-9-7-11(15)2-4-13(9)17/h1-4,6-7,16-17H,5H2

chave InChI

MDNWOSOZYLHTCG-UHFFFAOYSA-N

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Descrição geral

Bis(5-chloro-2-hydroxyphenyl)methane is a fungicide and is very effective against many celluloytic fungi, such as Penicillium, Aspergillus,Cladosporium and Trichoderma sp. It is a phenolic pesticide and undergoes photodegradation in the presence of visible-light absorber photosensitizer riboflavin.

Aplicação

Bis(5-chloro-2-hydroxyphenyl)methane can be used as a starting material to synthesize methyl aluminium-(2,2′-methylene-p-chloro-bisphenoxide), which is used as a catalyst for the ring opening polymerization (ROP) of cyclic esters. It can also be used as an organic building block to prepare phosphomides substituted with aminoacid esters for various biological studies.

Exoneração de responsabilidade

The product is not intended for use as a biocide under global biocide regulations, including but not limited to US EPA′s Federal Insecticide Fungicide and Rodenticide Act, European Biocidal Products Regulation, Canada’s Pest Management Regulatory Agency, Turkey’s Biocidal Products Regulation, Korea’s Consumer Chemical Products and Biocide Safety Management Act (K-BPR) and others.

Pictogramas

Exclamation markEnvironment

Palavra indicadora

Warning

Frases de perigo

Classificações de perigo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2

Código de classe de armazenamento

11 - Combustible Solids

Classe de risco de água (WGK)

WGK 3

Ponto de fulgor (°F)

Not applicable

Ponto de fulgor (°C)

Not applicable

Equipamento de proteção individual

dust mask type N95 (US), Eyeshields, Gloves


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Reaction of methyl aluminium-(2, 2?-methylene-p-chloro-bisphenoxide) with 2, 2?-di (hydroxymethyl) biphenyl: A new aluminium complex bearing two kinds of diolate ligands
Ziemkowska W, et al.
Journal of Organometallic Chemistry, 693(3), 369-373 (2008)
Synthesis and antimicrobial activity of 2,10-dichloro-6-substituted amino acid ester12H-dibenzo[d,g][1,3,2]dioxaphosphocin-6-oxides
BS Kumar, et al.
Bulgarian Chemical Communications, 41(4), 422-426 (2009)
F J Verhagen et al.
Applied and environmental microbiology, 64(9), 3225-3231 (1998-09-03)
Higher fungi have a widespread capacity for biosynthesis of organohalogens. Commonly occurring chloroaromatic fungal metabolites can end up in anaerobic microniches at the boundary of fungal colonies and wetland soils. The aim of this study was to investigate the environmental
Antoine Ghauch et al.
Journal of hazardous materials, 164(2-3), 665-674 (2008-09-30)
Palladium, ruthenium and silver were investigated as catalysts for the dechlorination of dichlorophen (DCP, 2,2'-methylenebis(4-chlorophenol)), an antimicrobial and anthelmintic agent largely used as algicide, fungicide and bactericide. Experiments were undertaken under oxic and anoxic conditions for experimental durations up to
J Langrand et al.
Clinical toxicology (Philadelphia, Pa.), 51(3), 178-181 (2013-03-12)
Human dichlorophen poisoning is rare. We aim to report a case of dichlorophen poisoning resulting in complete recovery despite life-threatening multiorgan failure and huge serum dichlorophen concentrations. Description of features and management in one dichlorophen-poisoned patient. After liquid-liquid extraction, dichlorophen

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