901368
[Ir(dFppy)2(dtbbpy)]PF6
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About This Item
Empirische Formel (Hill-System):
C40H36F10IrN4P
CAS-Nummer:
Molekulargewicht:
985.92
UNSPSC-Code:
51171641
NACRES:
NA.23
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Form
powder or crystals
Qualitätsniveau
Eignung der Reaktion
core: iridium
reagent type: catalyst
reaction type: Photocatalysis
mp (Schmelzpunkt)
>300 °C
Photokatalysatoraktivierung
465 nm
Anwendung
This photocatalyst readily facilitates alkynylation of carboxylic acids as well as the decarboxylative cross-coupling of oxalates via metallaphotoredox catalysis.
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)
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Produkt-Nr.
Beschreibung
Preisangaben
Lagerklassenschlüssel
11 - Combustible Solids
WGK
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
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Strongly Blue Luminescent Cationic Iridium(III) Complexes with an Electron-Rich Ancillary Ligand: Evaluation of Their Optoelectronic and Electrochemiluminescence Properties.
Ladouceur S,et al.
European Journal of Inorganic Chemistry, 2013, 5329-5343 (2013)
Franck Le Vaillant et al.
Angewandte Chemie (International ed. in English), 54(38), 11200-11204 (2015-07-28)
Alkynes are used as building blocks in synthetic and medicinal chemistry, chemical biology, and materials science. Therefore, efficient methods for their synthesis are the subject of intensive research. Herein, we report the direct synthesis of alkynes from readily available carboxylic
Timothy M Monos et al.
The Journal of organic chemistry, 81(16), 6988-6994 (2016-06-16)
We report a rapid, one-pot, operationally simple, and scalable preparation of valuable cationic heteroleptic iridium(III) polypyridyl photosensitizers. This method takes advantage of two consecutive microwave irradiation steps in the same reactor vial, avoiding the need for additional reaction purifications. A
Xiaheng Zhang et al.
Journal of the American Chemical Society (2016-10-11)
Alkyl oxalates, prepared from their corresponding alcohols, are engaged for the first time as carbon radical fragments in metallaphotoredox catalysis. In this report, we demonstrate that alcohols, native organic functional groups, can be readily activated with simple oxalyl chloride to
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