Direkt zum Inhalt
Merck
Alle Fotos(4)

Dokumente

209015

Sigma-Aldrich

Palladium(II)-acetylacetonat

99%

Synonym(e):

Palladium(II)-2,4-pentandionat, Pd(acac)2

Anmeldenzur Ansicht organisationsspezifischer und vertraglich vereinbarter Preise
Alle Fotos(4)

About This Item

Lineare Formel:
Pd(C5H7O2)2
CAS-Nummer:
14024-61-4
Molekulargewicht:
304.64
Beilstein:
4136188
EG-Nummer:
237-859-8
MDL-Nummer:
MFCD00000025
UNSPSC-Code:
12352103
PubChem Substanz-ID:
24852227
NACRES:
NA.23

Assay

99%

Form

powder

Eignung der Reaktion

core: aluminum
reagent type: catalyst

mp (Schmelzpunkt)

200-251 °C (dec.)

SMILES String

CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

InChIKey

JKDRQYIYVJVOPF-FDGPNNRMSA-L

Suchen Sie nach ähnlichen Produkten? Aufrufen Leitfaden zum Produktvergleich

Allgemeine Beschreibung

Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.

Anwendung

Catalyst employed in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Piktogramme

Exclamation mark
GHS07

Signalwort

Warning

H-Sätze

H319

Gefahreneinstufungen

Eye Irrit. 2

Lagerklassenschlüssel

11 - Combustible Solids

WGK

WGK 2

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Gloves

Analysenzertifikate (COA)

Suchen Sie nach Analysenzertifikate (COA), indem Sie die Lot-/Chargennummer des Produkts eingeben. Lot- und Chargennummern sind auf dem Produktetikett hinter den Wörtern ‘Lot’ oder ‘Batch’ (Lot oder Charge) zu finden.

Besitzen Sie dieses Produkt bereits?

In der Dokumentenbibliothek finden Sie die Dokumentation zu den Produkten, die Sie kürzlich erworben haben.

Die Dokumentenbibliothek aufrufen

Lukas J Goossen et al.
Journal of the American Chemical Society, 129(15), 4824-4833 (2007-03-23)
A new strategy for the regiospecific construction of unsymmetrical biaryls is presented, in which easily available salts of carboxylic acids are decarboxylated in situ to give arylmetal species that serve as the nucleophilic component in a catalytic cross-coupling reaction with
Sublimation and deposition behaviour of palladium (II) acetylacetonate.
Cominos V and Gavriilidis A.
The European Physical Journal - Applied Physics, 15(01), 23-33 (2001)
Nicolas Marion et al.
Accounts of chemical research, 41(11), 1440-1449 (2008-09-09)
Metal-catalyzed cross-coupling reactions, notably those permitting C-C bond formation, have witnessed a meteoritic development and are now routinely employed as a powerful synthetic tool both in academia and in industry. In this context, palladium is arguably the most studied transition
Sümeyra Diyarbakir et al.
ACS applied materials & interfaces, 7(5), 3199-3206 (2015-01-17)
Monodisperse CuPd alloy nanoparticles (NPs) were prepared by using a typical high-temperature organic solution phase protocol comprising the coreduction of copper(II) acetylacetonate and palladium(II) acetylacetonate by morpholine-borane complex in oleylamine and 1-octadecene solution at 80 °C. The presented synthesis protocol

Artikel

Heck Reaction

The Heck reaction is the palladium catalyzed cross-coupling reaction between alkenes and aryl or vinyl halides (or triflates) to afford substituted alkenes.

High Purity Metalorganic Precursors for CPV Device Fabrication

High Purity Metalorganic Precursors for CPV Device Fabrication

Nanowire Synthesis: From Top-Down to Bottom-Up

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

Unser Team von Wissenschaftlern verfügt über Erfahrung in allen Forschungsbereichen einschließlich Life Science, Materialwissenschaften, chemischer Synthese, Chromatographie, Analytik und vielen mehr..

Setzen Sie sich mit dem technischen Dienst in Verbindung.