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130001

Sigma-Aldrich

1-Methylpiperazin

99%

Synonym(e):

N-Methylpiperazine

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About This Item

Empirische Formel (Hill-System):
C5H12N2
CAS-Nummer:
109-01-3
Molekulargewicht:
100.16
Beilstein:
102724
EG-Nummer:
203-639-5
MDL-Nummer:
MFCD00005966
UNSPSC-Code:
12352100
PubChem Substanz-ID:
24847936
NACRES:
NA.22

Dampfdichte

3.5 (vs air)

Qualitätsniveau

200

Assay

99%

Form

liquid

Brechungsindex

n20/D 1.466 (lit.)

bp

138 °C (lit.)

Dichte

0.903 g/mL at 25 °C (lit.)

SMILES String

CN1CCNCC1

InChI

1S/C5H12N2/c1-7-4-2-6-3-5-7/h6H,2-5H2,1H3

InChIKey

PVOAHINGSUIXLS-UHFFFAOYSA-N

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Allgemeine Beschreibung

1-Methylpiperazine is a heterocyclic diamine used as a versatile building block and intermediate in organic synthesis.

Anwendung

1-Methylpiperazine was used as mimic template in the preparation of molecularly imprinted microspheres (MIMs). It was also used to prepare the difunctional strong anion-exchange stationary phase from a 1,4-diazacyclohexane derivative.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1B

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 1

Flammpunkt (°F)

88.7 °F - closed cup

Flammpunkt (°C)

31.5 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Analysenzertifikate (COA)

Lot/Batch Number
STBK9370
STBH6027
STBF7104V
STBF1692V
STBD7150V

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Juxiang Ruan et al.
Journal of chromatography. A, 1297, 77-84 (2013-06-01)
This paper reports the preparation of a novel, silica-based, strong anion-exchange stationary phase from a 1,4-diazacyclohexane derivative. To prepare the difunctional strong anion-exchange stationary phase, activated silica beads were first bonded with 3-chloropropyltriethoxysilane and then reacted with 1-methylpiperazine followed by
Hongyuan Yan et al.
The Analyst, 137(12), 2884-2890 (2012-05-04)
A highly selective molecularly imprinted solid-phase extraction (MISPE) combined with liquid chromatography-ultraviolet detection was developed for the simultaneous isolation and determination of four plant hormones including indole-3-acetic acid (IAA), indole-3-propionic acid (IPA), indole-3-butyric acid (IBA) and 1-naphthaleneacetic acid (NAA) in
H Welinder et al.
International archives of allergy and applied immunology, 79(3), 259-262 (1986-01-01)
The presence of specific IgE antibodies against conjugates between human serum albumin and piperazine, a compound previously known to cause occupational asthma, and N-methyl-piperazine, respectively, was demonstrated by RAST, RAST inhibition and skin prick tests in 2 asthmatic subjects occupationally
A R Roudman et al.
Journal of biomedical materials research, 39(4), 667-672 (1998-03-10)
Aminated poly(vinyl chloride) (PVC) membranes were prepared that had a Nernstian response over a wide range of pH. The reaction between PVC and methyl-piperazine (MePIP) in dimethylformamide (DMF) was studied over a wide range of time and temperature, and in
S A Leach et al.
Carcinogenesis, 8(12), 1907-1912 (1987-12-01)
Human exposure to endogenously formed N-nitroso compounds has frequently been suggested as a causative factor in carcinogenesis where this is related to chronic bacterial infection such as is seen in gastric achlorhydria. At least two distinct mechanisms of endogenous formation
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