115126

Methyl-10-undecenoat

96%

• Synonym(e): 10-Undecensäure-methylester, Undecylensäure-methylester
• Lineare Formel: CH₂=CH(CH₂)₈CO₂CH₃
• CAS-Nummer: 111-81-9
• Molekulargewicht: 198.30
• EG-Nummer: 203-910-8
• MDL-Nummer: MFCD00016689
• UNSPSC-Code: 12352100
• PubChem Substanz-ID: 24847199
• NACRES: NA.22

Eigenschaften

• Qualitätsniveau: 100
• Assay: 96%
• Brechungsindex: n20/D 1.437 (lit.)
• bp: 245 °C (lit.)
• Dichte: 0.882 g/mL at 25 °C (lit.)
• Funktionelle Gruppe: allyl; ester
• SMILES String: COC(=O)CCCCCCCCC=C
• InChI: 1S/C12H22O2/c1-3-4-5-6-7-8-9-10-11-12(13)14-2/h3H,1,4-11H2,2H3
• InChIKey: KISVAASFGZJBCY-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Methyl 10-undecenoate is the chain stopper in the polymerization of long-chain aliphatic α,ω-diene through acyclic diene metathesis (ADMET). This helps in tuning the molecular weight of the resulting polyester in a range varying from 10 to 45 kDa.

Anwendung

Methyl 10-undecenoate is an unsaturated fatty acid ester that can be used as a substrate:

• To prepare bifunctional polymer precursors via hydroformylation reaction.
• To synthesize α,ω-ester amides via aminocarbonylation in the presence of palladium catalyst.
• To modify commercial silicone monomer, 1,3,5,7-tetramethylcyclotetrasiloxane, for the preparation of silicone hollow nano/microstructures in water by hydrosilylation reaction.

Sicherheitshinweise

• Piktogramme: GHS07,GHS09
• Signalwort: Warning
• H-Sätze: H302 + H332,H410
• P-Sätze: P261 - P264 - P271 - P273 - P301 + P312 - P304 + P340 + P312
• Gefahreneinstufungen: Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1
• Lagerklassenschlüssel: 10 - Combustible liquids
• WGK: WGK 3
• Flammpunkt (°F): 239.0 °F - closed cup
• Flammpunkt (°C): 115 °C - closed cup
• Persönliche Schutzausrüstung: Eyeshields, Gloves