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Sigma-Aldrich

Iron(III) chloride

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anhydrous, powder, ≥99.99% trace metals basis

Synonym(s):

Ferric chloride, Iron trichloride, Molysite

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About This Item

Linear Formula:
FeCl3
CAS Number:
7705-08-0
Molecular Weight:
162.20
EC Number:
231-729-4
MDL number:
MFCD00011005
UNSPSC Code:
12352302
PubChem Substance ID:
24868641
NACRES:
NA.23

grade

anhydrous

vapor density

5.61 (vs air)

vapor pressure

1 mmHg ( 194 °C)

assay

≥99.99% trace metals basis

form

powder

reaction suitability

reagent type: catalyst
core: iron

greener alternative product characteristics

Catalysis
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sustainability

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impurities

≤100.0 ppm Trace Metal Analysis

mp

304 °C (lit.)

application(s)

battery manufacturing

greener alternative category

, Aligned

SMILES string

Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe/h3*1H;/q;;;+3/p-3

InChI key

RBTARNINKXHZNM-UHFFFAOYSA-K

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General description

Iron(III) chloride is brownish to black crystalline solid that is highly soluble in water. As a moderately strong Lewis acid, it highly reactive with bases and capable of forming complex ions. It is widely used as a iron precursor in the field of catalysis, solar cells and batteries.
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Application

Iron(III) chloride can be used:
  • As a precursor to fabricate nano-sized Fe-N-C catalysts for proton exchange membrane(PEM) fuel cells. FeCl3 iron precursor, helps to achieve the lowest charge transfer resistance and high peak power density.
  • As an oxidant to prepare FeOCl@PPy cathode materials for Li-ion batteries with good cycling stability.
  • As a precursor to fabricate amorphous multifunctional am-Fe–Bi/NF electrode for rechargeable Zinc-air batteries.
  • To synthesize Fe3O4@nanocellulose/TiCl nano fillers for dye-sensitized solar cells to reduce the crystallinity of the polymer.

The vapor-phase co-reductions with other metal halides by hydrogen results in finely divided intermetallics with applications as structural materials or compounds with useful thermoelectric, magnetic, and oxidation-resitance properties.

accessory

Product No.
Description
Pricing

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2

Storage Class

8B - Non-combustible corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Certificates of Analysis (COA)

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Enhancing graphene/CNT based electrochemical detection using magneto-nanobioprobes.
Jiang M, et al.
Material Matters, 2, 877-883 (2012)
Priyanka Sharma et al.
Scientific reports, 2, 877-877 (2012-11-21)
Graphene and related materials have come to the forefront of research in electrochemical sensors during recent years due to the promising properties of these nanomaterials. Further applications of these nanomaterials have been hampered by insufficient sensitivity offered by these nanohybrids
Photoredox chemistry of iron (III) chloride and iron (III) perchlorate in aqueous media. A comparative study.
David F and David PG.
The Journal of Physical Chemistry, 80(6), 579-583 (1976)
Abdelwareth A O Sarhan et al.
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Chen-Yu Chen et al.
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
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