93744
Bromopropylate
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(s):
Isopropyl 4,4′-dibromobenzilate, Phenisobromolate
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About This Item
Empirical Formula (Hill Notation):
C17H16Br2O3
CAS Number:
Molecular Weight:
428.12
Beilstein/REAXYS Number:
2152560
MDL number:
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grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
SMILES string
CC(C)OC(=O)C(O)(c1ccc(Br)cc1)c2ccc(Br)cc2
InChI
1S/C17H16Br2O3/c1-11(2)22-16(20)17(21,12-3-7-14(18)8-4-12)13-5-9-15(19)10-6-13/h3-11,21H,1-2H3
InChI key
FOANIXZHAMJWOI-UHFFFAOYSA-N
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General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Bromopropylate is a nonsystemic and nonpenetrating acaricide that remains on the peel of fruits and does not migrate into the pulp. It belongs to the family of organophosphate pesticides and is used in the cultivation of lemon trees and other crops. Bromopropylate primarily acts by interfering with the respiratory system. It affects the mitochondria by inhibiting key enzymatic activities and ATP generation, which leads to the formation of reactive oxygen species, and destroys proteins, membranes, unsaturated fatty acids, DNA, etc.
Bromopropylate has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
The use of bromopropylate has been banned across the European Union. Maximum residue levels (MRLs) have been set according to Reg. (EU) No 310/2011 for bromopropylate for various products of plant and animal origin from 0.01 to 0.05 mg/kg.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Bromopropylate is a nonsystemic and nonpenetrating acaricide that remains on the peel of fruits and does not migrate into the pulp. It belongs to the family of organophosphate pesticides and is used in the cultivation of lemon trees and other crops. Bromopropylate primarily acts by interfering with the respiratory system. It affects the mitochondria by inhibiting key enzymatic activities and ATP generation, which leads to the formation of reactive oxygen species, and destroys proteins, membranes, unsaturated fatty acids, DNA, etc.
Bromopropylate has to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
The use of bromopropylate has been banned across the European Union. Maximum residue levels (MRLs) have been set according to Reg. (EU) No 310/2011 for bromopropylate for various products of plant and animal origin from 0.01 to 0.05 mg/kg.
Application
The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques. Bromopropylate CRM may also find following uses:
- To elucidate the inhibition of plasma and brain acetylcholinesterase activity in Wistar rats with a mixture of 5 pesticides: chlorpyrifos, alphacypermetrin, bromopropylate, carbendazim, and mancozeb
- Study the degradation processes of bromopropylate, coumaphos, chlordimeform, cymiazole, flumethrin, and fluvalinate in aqueous media by HPLC
- To develop a liquid-phase microextraction method using deep eutectic solvent for extraction and preconcentration of diazinon, metalaxyl, bromopropylate, oxadiazon, and fenazaquin pesticides from samples such as grape and sour cherry juices, fresh beet, cucumber, potato, and tomato followed by gas chromatography-flame ionization detection
- To develop a multi-residue method for the determination of azinphos methyl, bromopropylate, chlorpyrifos, dimethoate, parathion methyl, and phosalone in apricots and peaches using negative chemical ionization ion trap technology
- Simultaneous determination of amitraz, bromopropylate, coumaphos, cymiazole, and fluvalinate residues in honey by solid-phase extraction and GC-MS
Recommended products
Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Konstantinos S Liapis et al.
Journal of chromatography. A, 996(1-2), 181-187 (2003-07-02)
A rapid, selective and sensitive multi-residue method for the determination of six common pesticides in stone fruit samples is described. The proposed method involves the extraction of the pesticides with the use of acetone solvent followed by liquid-liquid partition with
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