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230391

Sigma-Aldrich

Magnesium sulfate heptahydrate

ACS reagent, ≥98%

Synonym(s):
Epsom salts
Linear Formula:
MgSO4 · 7H2O
CAS Number:
Molecular Weight:
246.47
EC Number:
MDL number:
eCl@ss:
38030409
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent

Quality Level

vapor density

<0.01 (vs air)

vapor pressure

<0.1 mmHg ( 20 °C)

Assay

≥98%
98.0-102.0% (ACS specification)

form

crystals

impurities

≤0.005% insolubles

pH

5.0-8.2 (25 °C, 5%)

anion traces

chloride (Cl-): ≤5 ppm
nitrate (NO3-): ≤0.002%

cation traces

Ca: ≤0.02%
Fe: ≤5 ppm
K: ≤0.005%
Mn: ≤5 ppm
NH4+: ≤0.002%
Na: ≤0.005%
Sr: ≤0.005%
heavy metals: ≤5 ppm (by ICP-OES)

SMILES string

O.O.O.O.O.O.O.[Mg++].[O-]S([O-])(=O)=O

InChI

1S/Mg.H2O4S.7H2O/c;1-5(2,3)4;;;;;;;/h;(H2,1,2,3,4);7*1H2/q+2;;;;;;;;/p-2

InChI key

WRUGWIBCXHJTDG-UHFFFAOYSA-L

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This Item
1.932451.93645M1880
grade

ACS reagent

grade

ACS reagent

grade

-

grade

-

vapor pressure

<0.1 mmHg ( 20 °C)

vapor pressure

<0.1 mmHg ( 20 °C)

vapor pressure

<0.1 mmHg ( 20 °C)

vapor pressure

<0.1 mmHg ( 20 °C)

assay

≥98%, 98.0-102.0% (ACS specification)

assay

-

assay

-

assay

≥99.0%

form

crystals

form

-

form

-

form

powder or crystals

impurities

≤0.005% insolubles

impurities

-

impurities

-

impurities

-

pH

5.0-8.2 (25 °C, 5%)

pH

-

pH

-

pH

5-8 (50 g/L)

General description

Magnesium sulfate heptahydrate is a hydrated salt of magnesium. It is commonly used as a catalyst in organic synthesis.

Application

Magnesium sulfate heptahydrate can be used as a Lewis acid catalyst to synthesize:      
  • Phenazine and quinoxaline derivatives via a condensation reaction between o-phenylenediamines and 1,2-dicarbonyl compounds.
  • Imidazole derivatives via one-pot multicomponent condensation reaction of aromatic aldehydes, benzil, aliphatic, and aromatic primary amines.

NaBH4 supported on MgSO4 7H2O can be used as an efficient catalyst for the reduction of α, β-unsaturated carbonyl compounds to corresponding alcohols.

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

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