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Tridodecylmethylammonium nitrate

Selectophore™, ≥99.0%

Synonym(s):

Methyltridodecylammonium nitrate

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About This Item

Linear Formula:
[CH3(CH2)11]3N(NO3)CH3
CAS Number:
13533-59-0
Molecular Weight:
599.03
MDL number:
MFCD00145447
UNSPSC Code:
26111700
PubChem Substance ID:
329770065
NACRES:
NB.61

grade

for ion-selective electrodes

Quality Level

200

product line

Selectophore™

assay

≥99.0% (T)
≥99.0%

form

powder

SMILES string

[O-][N+]([O-])=O.CCCCCCCCCCCC[N+](C)(CCCCCCCCCCCC)CCCCCCCCCCCC

InChI

1S/C37H78N.NO3/c1-5-8-11-14-17-20-23-26-29-32-35-38(4,36-33-30-27-24-21-18-15-12-9-6-2)37-34-31-28-25-22-19-16-13-10-7-3;2-1(3)4/h5-37H2,1-4H3;/q+1;-1

InChI key

AMIVMTKBZPOVKF-UHFFFAOYSA-N

General description

Tridodecylmethylammonium nitrate (TDMAN) is a nitrate ionophore which has good selectivity for nitrate more than chloride.
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Application

Selected application examples
TDMAN has been used in preparing liquid ion-selective electrode membrane during coulometric analysis of nitrate from fresh water samples.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Highly lipophilic electroactive component (nitrate ion-exchange) for solvent polymeric electrodes; used in ion-selective field effect transistors; Determination of nitrate in water, soil extracts and in agriculture by ion-selective electrode

Legal Information

Selectophore is a trademark of Merck KGaA, Darmstadt, Germany

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pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H315

Hazard Classifications

Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD0473
BCBK9546V
BCBK0387V
014928/1V
014928/1

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S. Wakida et al.
Bunseki Kogaku, 38, 510-510 (1989)
V. Kratochvil
Ceskoslovenska Hygiena, 31, 355-355 (1986)
Thin layer coulometric determination of nitrate in fresh waters.
Sohail M
Analytica Chimica Acta, 744, 39-44 (2012)
Hemin Wang et al.
Analytica chimica acta, 1129, 136-142 (2020-09-07)
Traditional potentiometric NO3--selective electrodes suffer from a fundamental limitation of the Nernst slope (59.1 mV/dec at 25 °C) due to the relationship between the potential and the logarithmic of ionic activity. Herein, a coulometric signal readout is proposed instead of the
D. Wegmann et al.
Mikrochim. Acta III, 1-1 (1984)

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