88413
1-(2-Thiazolylazo)-2-naphthol
for spectrophotometric det. of Cd, Co, Cu, Mn, Ni, Tl, ≥99.0%
Synonym(s):
2-(2-Hydroxy-1-naphthylazo)thiazole, TAN
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About This Item
Empirical Formula (Hill Notation):
C13H9N3OS
CAS Number:
Molecular Weight:
255.30
Beilstein/REAXYS Number:
21172
EC Number:
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:
NACRES:
NA.21
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Quality Level
assay
≥99.0% (CHN)
≥99.0%
form
powder
quality
for spectrophotometric det. of Cd, Co, Cu, Mn, Ni, Tl
technique(s)
UV/Vis spectroscopy: suitable
mp
138-139 °C
solubility
methanol: 10 mg/mL, clear
SMILES string
Oc1ccc2ccccc2c1\N=N\c3nccs3
InChI
1S/C13H9N3OS/c17-11-6-5-9-3-1-2-4-10(9)12(11)15-16-13-14-7-8-18-13/h1-8,17H/b16-15+
InChI key
IOMXCGDXEUDZAK-FOCLMDBBSA-N
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Other Notes
Reagent for the extraction and spectrophotometric determination of metals, metallochromic indicator
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Serife Tokalioğlu et al.
Environmental monitoring and assessment, 152(1-4), 369-377 (2008-05-20)
A new method for separation and preconcentration of trace amounts of Cu(II), Ni(II), Pb(II), Cd(II) and Mn(II) ions in various matrices was proposed. The method is based on the adsorption and chelation of the metal ions on a column containing
Y Sumi et al.
Histochemistry, 87(4), 327-329 (1987-01-01)
We describe a new autoradiographic technique for differentially demonstrating the presence of trace amounts of cadmium that remains unbound to metallothionein in tissue sections. This procedure involves [14C-1,4,5,8-naphthol]-1-(2-thiazolylazo)-2-naphthol (TAN) instead of a metal radioisotope. Tissue sections were stained using labeled
K C Teo et al.
The Analyst, 126(4), 534-537 (2001-05-09)
Cloud point extraction has been used for the preconcentration of manganese, after the formation of a complex with 1-(2-thiazolylazo)-2-naphthol (TAN), and later analysis by flame atomic absorption spectrometry using octylphenoxypolyethoxyethanol (Triton X-114) as surfactant. The chemical variables affecting the separation
Puja Prasad et al.
Chemical communications (Cambridge, England), 47(13), 3954-3956 (2011-02-22)
Planar triazinium cationic species, from VO(2+)-assisted cyclization of 1-(2-thiazolylazo)-2-naphthol, shows efficient DNA intercalative binding, visible light-induced anaerobic plasmid DNA photocleavage activity and photocytotoxicity in HeLa and MCF-7 cancer cells by an apoptotic pathway with selective localization of the compound in
M M Omar et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 61(5), 929-936 (2005-02-03)
The synthesis and characterization of Mn(II), Fe(III), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), Pd(II) and UO2(II) chelates of 1-(2-thiazolylazo)-2-naphthalenol (TAN) were reported. The dissociation constants of the ligand and the stability constants of the metal complexes were calculated pH-metrically at 25
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