06061

Allyl phenyl sulfone

purum, ≥98.0% (GC)

• Synonym(s): (2-Propen-1-ylsulfonyl)benzene, (2-Propenylsulfonyl)benzene, (Allylsulfonyl)benzene, Phenyl 2-propenyl sulfone
• Linear Formula: C₆H₅SO₂CH₂CH=CH₂
• CAS Number: 16212-05-8
• Molecular Weight: 182.24
• Beilstein/REAXYS Number: 1863561
• EC Number: 240-338-8
• MDL number: MFCD00014739
• UNSPSC Code: 12352100
• PubChem Substance ID: 329748204
• NACRES: NA.22

Properties

• grade: purum
• Quality Level: 200
• assay: ≥98.0% (GC)
• form: liquid
• refractive index: n20/D 1.548 (lit.); n20/D 1.548
• bp: 110-113 °C/0.5 mmHg (lit.)
• density: 1.189 g/mL at 25 °C (lit.)
• storage temp.: 2-8°C
• SMILES string: C=CCS(=O)(=O)c1ccccc1
• InChI: 1S/C9H10O2S/c1-2-8-12(10,11)9-6-4-3-5-7-9/h2-7H,1,8H2
• InChI key: KYPIULIVYSQNNT-UHFFFAOYSA-N

Description

Application

Possible usages of allyl phenyl sulfone:

• It can undergo isomerization by the nonionic proazaphosphatrane catalysts under mild reaction conditions.
• It can react with epoxymesylate to give cycloalkane derivative. This method has been employed in the synthesis of marine eicosanoid bacillariolides I-III.
• It can undergo electrocatalytic additions to vinyl sulfones catalyzed by an electrogenerated base.

Starting material for the preparation of 1-alkyl-2-methylethenes; Michael additions to enones; Synthesis of α,β-unsaturated nitriles

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: 235.4 °F - closed cup
• flash_point_c: 113 °C - closed cup
• ppe: Eyeshields, Gloves, type ABEK (EN14387) respirator filter