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Key Documents

05-4600

Sigma-Aldrich

Chromium(VI) oxide

SAJ special grade, ≥98.0%

Synonym(s):

Chromic anhydride

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About This Item

Empirical Formula (Hill Notation):
CrO3
CAS Number:
Molecular Weight:
99.99
EC Number:
MDL number:
UNSPSC Code:
12352303
PubChem Substance ID:

grade

SAJ special grade

assay

≥98.0%

form

solid

availability

available only in Japan

pH

<1 (20 °C, 100 g/L)

mp

196 °C (dec.) (lit.)

SMILES string

O=[Cr](=O)=O

InChI

1S/Cr.3O

InChI key

WGLPBDUCMAPZCE-UHFFFAOYSA-N

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signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Eye Dam. 1 - Muta. 1B - Ox. Sol. 1 - Repr. 2 - Resp. Sens. 1 - Skin Corr. 1A - Skin Sens. 1 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Respiratory system

Storage Class

5.1A - Strongly oxidizing hazardous materials

wgk_germany

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges


Certificates of Analysis (COA)

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S Kondo et al.
European journal of biochemistry, 200(3), 689-698 (1991-09-15)
The chemical structure of the saccharide portion of Vibrio parahaemolyticus serotype 012 lipopolysaccharide was studied. Using chemical degradation and modification, as well as methylation analysis in combination with GLC-MS, laser-desorption mass spectrometry and 1H-NMR and 13C-NMR spectroscopy, the carbohydrate backbone
S Y Shiau et al.
The Journal of nutrition, 123(10), 1747-1753 (1993-10-01)
An experiment was conducted to study the influence of three different forms of chromium (CrCl3.6H2O, Na2CrO4.4H2O and Cr2O3) on the utilization of two carbohydrates (glucose and cornstarch) by juvenile hybrid tilapia (Oreochromis niloticus x O. aureus). Average initial body weight
Li-Hong Huang et al.
Molecules (Basel, Switzerland), 10(7), 794-797 (2007-11-17)
A selective oxidation of primary alcohols to the corresponding aldehydes by shaking with chromium trioxide supported on aluminium silicate at room temperature under solvent free conditions is reported. This new procedure can also oxidise secondary alcohols.
Reem H Elbekai et al.
Free radical biology & medicine, 39(11), 1499-1511 (2005-11-09)
Heavy metals alter the capacity of AhR ligands to induce the bioactivating phase I and the detoxifying phase II xenobiotic-metabolizing enzymes but the mechanism(s) remain unknown. In the present study, we evaluated the role of As(3+)-, Cd(2+)-, and Cr(6+)-induced oxidative
Francis Pierre et al.
International archives of occupational and environmental health, 81(3), 321-329 (2007-07-03)
This study is concerned with two specific chromium (Cr) exposure situations at a hard-process electroplating company. Its aims are to define variations in urinary Cr concentration and to clarify their exposure relationships. Airborne chromium exposure and urinary excretion were measured

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