1.03168

Eriochrome blue-black B (C.I. 14640)

metal indicator

• Synonym(s): Eriochrome blue-black B (C.I. 14640), 2-Hydroxy-1-(1-hydroxy-2-naphthylazo)-naphthalene-4-sulfonic acid sodium salt
• Empirical Formula (Hill Notation): C₂₀H₁₃N₂NaO₅S
• CAS Number: 3564-14-5
• Molecular Weight: 416.38
• UNSPSC Code: 12352107
• EC Index Number: 222-639-6
• NACRES: NA.21

Properties

• product name: Eriochrome blue-black B (C.I. 14640), metal indicator
• Quality Level: 200
• form: solid
• potency: >5000 mg/kg LD₅₀, oral (Rat)
• loss: ≤10% loss on drying, 110°C
• pH: 9.5 (20 °C, 10 g/L in H₂O)
• solubility: 20 g/L
• bulk density: 540 kg/m³
• λmax: 634-644 nm (buffer pH 10.0)
• storage temp.: 15-25°C
• InChI: 1S/C20H14N2O5S.Na/c23-17-11-18(28(25,26)27)14-7-3-4-8-15(14)19(17)22-21-16-10-9-12-5-1-2-6-13(12)20(16)24;/h1-11,21,24H,(H,25,26,27);/q;+1/p-1/b22-19-;
• InChI key: YRFCCVCSEVISHI-GXTSIBQPSA-M

Description

Application

• New palladium-oxazoline complexes: Synthesis and evaluation of the optical properties and the catalytic power during the oxidation of textile dyes.: This study examines new palladium-oxazoline complexes, focusing on their synthesis and evaluation of their optical properties and catalytic power in the oxidation of textile dyes, including Eriochrome Blue-Black B (Hassani et al., 2015).


• Wet air and catalytic wet air oxidation of several azodyes from wastewaters: the beneficial role of catalysis.: This research explores the application of wet air and catalytic wet air oxidation processes to degrade various azo dyes in wastewaters, highlighting the positive impact of catalysis in enhancing degradation efficiency, potentially applicable to Eriochrome Blue-Black B (Rodríguez et al., 2009).

Analysis Note

Identity (UV/VIS-Spectrum): passes test
Absorption maximum λ_max. (buffer pH 10.0): 634 - 644 nm
Spec. Absorptivity A 1%/1cm (λ_max; 0.025 g/l; buffer pH 10.0; calculated on anhydrous substance): 220 - 320
Loss on drying (110 °C): ≤ 10 %
Suitability as indicator (for metal titration): passes test

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H319
• pcodes: P264 - P280 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable