B32807

Benzyltriphenylphosphonium chloride

99%

• Synonym(s): BTPPC, NSC 116712, Triphenyl(phenylmethyl)phosphonium chloride
• Linear Formula: C₆H₅CH₂P(Cl)(C₆H₅)₃
• CAS Number: 1100-88-5
• Molecular Weight: 388.87
• Beilstein/REAXYS Number: 3599868
• EC Number: 214-154-3
• MDL number: MFCD00011913
• UNSPSC Code: 12352107
• PubChem Substance ID: 24891707
• NACRES: NA.22

Properties

• Quality Level: 200
• assay: 99%
• form: powder
• reaction suitability: reaction type: C-C Bond Formation
• mp: ≥300 °C (lit.)
• SMILES string: [Cl-].C(c1ccccc1)[P+](c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C25H22P.ClH/c1-5-13-22(14-6-1)21-26(23-15-7-2-8-16-23,24-17-9-3-10-18-24)25-19-11-4-12-20-25;/h1-20H,21H2;1H/q+1;/p-1
• InChI key: USFRYJRPHFMVBZ-UHFFFAOYSA-M

Description

Application

Benzyltriphenylphosphonium chloride can be used as a reactant for the synthesis of:

• Platinum chloro-tetrazole complexes via azidation.
• Trans-stilbenes and cinnamates via Wittig olefination.
• Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment.
• Pentiptycenes for use as light-driven molecular brakes.
• Archipelago structures for formation of petroleum asphaltenes.

It is also used as a crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites.

Crosslinking agent for tube-like natural halloysite / fluorelastomer nanocomposites

Reactant for synthesis of:

• Platinum chloro tetrazole complexes via azidation
• Trans-stilbenes and cinnamates via Wittig olefination
• Achiral N-hydroxyformamide inhibitors of ADAM-TS4 and ADAM-TS5 for osteoarthritis treatment
• Pentiptycenes for use as light-driven molecular brakes

Reactant for formation of archipelago structures for formation of petroleum asphaltenes

Safety Information

• pictograms: GHS06,GHS08,GHS05,GHS09
• signalword: Danger
• hcodes: H300 + H330,H318,H335,H372,H410
• pcodes: P260 - P273 - P280 - P304 + P340 + P310 - P305 + P351 + P338 - P314
• Hazard Classifications: Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT RE 1 - STOT SE 3
• target_organs: Lungs,nasal cavity, Respiratory system
• Storage Class: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• wgk_germany: WGK 3
• flash_point_f: 572.0 °F - closed cup
• flash_point_c: 300 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges