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Key Documents

ALD00374

Sigma-Aldrich

L-Fmoc-3-fluorophenylalanine

Synonym(s):

Fmoc-Phe(3-F)-OH, Fmoc-3-fluoro-L-phenylalanine

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About This Item

Empirical Formula (Hill Notation):
C24H20FNO4
CAS Number:
Molecular Weight:
405.42
MDL number:
UNSPSC Code:
12352209
PubChem Substance ID:
NACRES:
NA.22

form

solid

Quality Level

reaction suitability

reaction type: Fmoc solid-phase peptide synthesis

color

beige

application(s)

peptide synthesis

functional group

Fmoc

storage temp.

2-8°C

SMILES string

FC1=CC=CC(C[C@H](NC(OCC2C3=C(C4=C2C=CC=C4)C=CC=C3)=O)C(O)=O)=C1

InChI

1S/C24H20FNO4/c25-16-7-5-6-15(12-16)13-22(23(27)28)26-24(29)30-14-21-19-10-3-1-8-17(19)18-9-2-4-11-20(18)21/h1-12,21-22H,13-14H2,(H,26,29)(H,27,28)/t22-/m0/s1

InChI key

DWSDVARCJDOADL-QFIPXVFZSA-N

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Application

Phenylalanine derivative was introduced in collaboration with Yu and coworkers in reflection to a methodology reported in C-H Activation.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Related Content

The Yu program centers around the discovery of catalytic carbon–carbon and carbon–heteroatom bond forming reactions based on C–H activation. Target transformations are selected to enable 1) the use of simple and abundant starting materials such as aliphatic acids, amines and alcohols, and 2) disconnections that drastically shorten the synthesis of a drug molecule or a major class of biologically active compounds.

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