ALD00350

N-[(9H-Fluoren-9-ylmethoxy)carbonyl]-2-methoxy-L-phenylalanine

95% (HPLC)

• Empirical Formula (Hill Notation): C₂₅H₂₃NO₅
• Molecular Weight: 417.45
• MDL number: MFCD01317011
• UNSPSC Code: 12352209
• PubChem Substance ID: 329772654
• NACRES: NA.22

Properties

• assay: 95% (HPLC)
• form: solid
• reaction suitability: reaction type: solution phase peptide synthesis
• mp: 171-176 °C
• application(s): peptide synthesis
• storage temp.: 2-8°C
• SMILES string: OC([C@@H](NC(OCC1C(C=CC=C2)=C2C3=C1C=CC=C3)=O)CC4=CC=CC=C4OC)=O
• InChI: 1S/C25H23NO5/c1-30-23-13-7-2-8-16(23)14-22(24(27)28)26-25(29)31-15-21-19-11-5-3-9-17(19)18-10-4-6-12-20(18)21/h2-13,21-22H,14-15H2,1H3,(H,26,29)(H,27,28)/t22-/m0/s1
• InChI key: CBCSNZJHURMDMO-QFIPXVFZSA-N

Description

Application

Unnatrual amino acid was derived from a C-H Activation methodology developed by Jin-Quan Yu and coworkers. The Pd-mediated C-C bond formation can be made in tandem with 2-Methylpyridine (Aldrich 109835).

Other Notes

Ligand-Controlled C(sp³)–H Arylation and Olefination in Synthesis of Unnatural Chiral α–Amino Acids

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable