932671

4,7-Diphenyl-1,10-phenanthroline

• Synonym(s): Bathophenanthroline, 4,7-Diphenyl-1,10-phenanthroline, BPhen
• Empirical Formula (Hill Notation): C₂₄H₁₆N₂
• CAS Number: 1662-01-7
• Molecular Weight: 332.40
• Beilstein/REAXYS Number: 261048
• MDL number: MFCD00004976
• UNSPSC Code: 23151817
• NACRES: NA.21

Properties

• grade: sublimed grade
• Quality Level: 100
• description: µe ≈ 3.0 x 10^-4 cm²V^-1s^-1
• assay: ≥99% (H-NMR)
• form: powder
• loss: 0.5% TGA, >240ºC (weight loss)
• mp: 218-220 °C (lit.)
• solubility: THF: soluble; chloroform: soluble; dichloromethane: soluble
• λmax: 272 nm in THF
• fluorescence: λ_em 379 nm in THF
• orbital energy: HOMO 6.4 eV ; LUMO 3.0 eV
• SMILES string: c1ccc(cc1)-c2ccnc3c2ccc4c(ccnc34)-c5ccccc5
• InChI: 1S/C24H16N2/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18/h1-16H
• InChI key: DHDHJYNTEFLIHY-UHFFFAOYSA-N

Description

Application

Intermolecular charge-transfer states at the interface between electron donating (D) and accepting (A) materials are crucial for the operation of organic electronics, such as solar cells, transistors and organic light-emitting diodes (OLEDs). The 4,7-Diphenyl-1,10-phenanthroline, also known as Bathophenanthroline (Bphen) enables use as Electron Transport / Hole Blocking Layer (ETL / HBL) in your organic electronic devices. It has a μe of about 3.0 x 10^-4 cm² V⁻¹ s⁻¹ and is solution-processable.

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable