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926795

Sigma-Aldrich

3CzEPAIPN

≥95%

Synonym(s):

2,4,5-Tri(9H-carbazol-9-yl)-6-(ethyl(phenyl)amino)isophthalonitrile

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About This Item

Empirical Formula (Hill Notation):
C52H34N6
CAS Number:
2662263-39-8
Molecular Weight:
742.87
UNSPSC Code:
12352101
NACRES:
NA.21

Quality Level

100

assay

≥95%

form

powder

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

SMILES string

N#CC1=C(N2C(C=CC=C3)=C3C4=C2C=CC=C4)C(C#N)=C(N5C(C=CC=C6)=C6C7=C5C=CC=C7)C(N8C(C=CC=C9)=C9C%10=C8C=CC=C%10)=C1N(CC)C%11=CC=CC=C%11

Related Categories

Application

3CzEPAIPN is cyanoarene-based donor-acceptor photocatalyst.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Unveiling Extreme Photoreduction Potentials of Donor−Acceptor Cyanoarenes to Access Aryl Radicals from Aryl Chlorides

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Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Jinhui Xu et al.
Journal of the American Chemical Society, 143(33), 13266-13273 (2021-08-26)
Since the seminal work of Zhang in 2016, donor-acceptor cyanoarene-based fluorophores, such as 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN), have been widely applied in photoredox catalysis and used as excellent metal-free alternatives to noble metal Ir- and Ru-based photocatalysts. However, all the reported photoredox

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