925764
Tris(4-carbazoyl-9-ylphenyl)amine
≥97%
Synonym(s):
TCTA
About This Item
Recommended Products
Quality Level
assay
≥97%
form
(Solid/Powder)
color
light yellow, transparent
mp
179-183 °C
λmax
385 nm (in THF)
orbital energy
HOMO 5.83 eV
LUMO 2.43 eV
UV absorption
λ: 293 nm Amax: in THF
λ: 326 nm Amax: in THF
storage temp.
2-8°C
SMILES string
c1ccc2c(c1)n(-c3ccc(cc3)N(c4ccc(cc4)-n5c6ccccc6c7ccccc57)c8ccc(cc8)-n9c%10ccccc%10c%11ccccc9%11)c%12ccccc2%12
InChI
1S/C54H36N4/c1-7-19-49-43(13-1)44-14-2-8-20-50(44)56(49)40-31-25-37(26-32-40)55(38-27-33-41(34-28-38)57-51-21-9-3-15-45(51)46-16-4-10-22-52(46)57)39-29-35-42(36-30-39)58-53-23-11-5-17-47(53)48-18-6-12-24-54(48)58/h1-36H
InChI key
AWXGSYPUMWKTBR-UHFFFAOYSA-N
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Application
TCTA is widely used as a hole-transport and hole-injection material in light-emitting diodes and perovskite solar cells.
TCTA is a very popular phosphorescent host material due to its large band gap (Eg = 3.4 eV) for green, red and white phosphorescent organic light-emitting diodes (PhOLEDs).
Examples of OLED device performance:
1. ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al
Color: red
Max. Luminance: 24529 Cd/m2
Max. EQE: 17 %
Turn-On Voltage: 2.7 V
2. ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
Color: green
Max. Luminance: 207839 Cd/m2
Max. EQE: 21.6 %
Turn-On Voltage: 2.1 V
3. ITO/PEDOT:PSS/NPD/TCTA/m-CBTZ:FIrpic (10 wt%)/DPPS/TAZ/LiF/Al
Color: blue
Max. Luminance: 29500 Cd/m2
Max. EQE: 8.8 %
Turn-On Voltage: 3.5 V
4. ITO/PEDOT:PSS/NPD/TCTA/m-CBTZ:Ir(Bt)2(acac) (10%)/TPBI/LiF/Al
Color: yellow
Max. Luminance: 106000 Cd/m2
Max. EQE: 17.5 %
Turn-On Voltage: 3 V
Related product
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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