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918083

Sigma-Aldrich

2,9-Dimethyl-1,10-phenanthroline nickel (ll) bromide

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About This Item

Empirical Formula (Hill Notation):
C14H12Br2N2Ni
CAS Number:
Molecular Weight:
426.76
UNSPSC Code:
12352200

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

mp

>300 °C

Application

2,9-Dimethyl-1,10-phenanthroline nickel (ll) bromide is a Ni precatalyst used for a variety of cross-coupling reactions.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Qing-Yuan Meng et al.
Angewandte Chemie (International ed. in English), 56(43), 13426-13430 (2017-08-24)
We report the efficient carboxylation of bromides and triflates with K2 CO3 as the source of CO2 in the presence of an organic photocatalyst in combination with a nickel complex under visible light irradiation at room temperature. The reaction is

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