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912948

Sigma-Aldrich

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6

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About This Item

Empirical Formula (Hill Notation):
C44H34F20IrN4P
CAS Number:
Molecular Weight:
1221.93
UNSPSC Code:
12352101
NACRES:
NA.22

form

powder

Quality Level

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

378 °C

Application

Ir[FCF3(CF3)ppy]2(dtbbpy)PF6 is a versatile photocatalyst that can be used for a variety of synthetic transformations including the α-arylation of alcohols.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Related product

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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Jack Twilton et al.
Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation

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