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900583

Sigma-Aldrich

Li-Li Auxiliary

≥95%

Synonym(s):

N-(2-Cyanophenethyl)-4-nitrobenzenesulfonamide

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About This Item

Empirical Formula (Hill Notation):
C15H13N3O4S
Molecular Weight:
331.35
UNSPSC Code:
12352101

assay

≥95%

form

powder or crystals

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

Application

Li-Li auxiliary assists the direct meta-C–H olefination and acetoxylation of benzoic acids through a nitrile-based sulfonamide template under mild conditions. The expansion of substrate scope regardless of substitution patterns and steric biases will enable the wide adoption of this protocol to the synthesis of drug molecules and natural products, of which benzoic acids are significant motifs.

Other Notes

Pd(II)-catalysed meta-C–H functionalizations of benzoic acid derivatives

Related product

Product No.
Description
Pricing

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Li Group – Professor Product Portal

Research in Prof. Gang Li's lab includes transition-metal-catalyzed C–H bond activation reactions and small molecule activation.

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