Skip to Content
MilliporeSigma
All Photos(2)

Key Documents

900275

Sigma-Aldrich

(t-Bu)PhCPhos

95%

Synonym(s):

2-[(tert-Butyl)phenylphosphino]-2′,6′-bis(N,N-dimethylamino)biphenyl

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C26H33N2P
CAS Number:
Molecular Weight:
404.53
UNSPSC Code:
12352200
NACRES:
NA.22

Quality Level

assay

95%

form

powder or crystals

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

reagent type: ligand

mp

112 °C

functional group

phosphine

Application

(t-Bu)PhCPhos is the Pd G3 complex, from the Buchwald group offers best-in-class performance in the arylation of sterically hindered primary amines.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Sorry, we don't have COAs for this product available online at this time.

If you need assistance, please contact Customer Support.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Paula Ruiz-Castillo et al.
Journal of the American Chemical Society, 137(8), 3085-3092 (2015-02-05)
We report the Pd-catalyzed arylation of very hindered α,α,α-trisubstituted primary amines. Kinetics-based mechanistic analysis and rational design have led to the development of two biarylphosphine ligands that allow the transformation to proceed with excellent efficiency. The process was effective in

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service