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72262

Sigma-Aldrich

Nickel (IV) oxide

technical, oxidizing agent, ~30% active peroxide basis

Synonym(s):

Nickel dioxide, Nickel oxide

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About This Item

Empirical Formula (Hill Notation):
NiO2
CAS Number:
12035-36-8
Molecular Weight:
90.69
EC Number:
234-823-3
MDL number:
MFCD00011143
UNSPSC Code:
12352000
PubChem Substance ID:
57652407
NACRES:
NA.22

grade

oxidizing agent
technical

Quality Level

100

form

powder

reaction suitability

core: nickel
reagent type: catalyst
reagent type: oxidant

concentration

~30% (active peroxide)

SMILES string

O=[Ni]O[Ni]=O

InChI

1S/2Ni.3O

InChI key

PZFKDUMHDHEBLD-UHFFFAOYSA-N

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Application

Catalyst for:
  • One-dimensional oxide-metal hybrid structures and site-specific enhanced reactivity for CO oxidation
  • Microwave induced catalytic degradation of crystal violet

Used to study differences in reactivity trends for carbon monoxide catalyzed oxidation caused by anionic transition metal oxide clusters

Reagent:
  • For solvent-free oxidation of alcohols†
  • For chemoselective oxidation of organic compounds using inductive heating
  • To improve the synthesis of methoxy cephalosporin′s intermediate

Other Notes

Oxidant for the transformation of alcohols into acids and hydrazones into diazoalkanes

signalword

Danger

Hazard Classifications

Aquatic Chronic 4 - Carc. 1A Inhalation - Ox. Sol. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

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Zachary Daniels et al.
Materials (Basel, Switzerland), 12(18) (2019-09-11)
Described herein is a novel method, Reduction Expansion Synthesis-Sintered Metal (RES-SM), to create a sintered metal body of a designed shape at ambient pressure, hundreds of degrees below the metal melting temperature. The precursor to the metal part is a
M. Bohshar et al. et al.
Meth. Org. Chem., E14(b), 1007-1007 (1990)
K. Nakagawa et al.
The Journal of Organic Chemistry, 27, 1597-1597 (1962)
Rut Sanchis et al.
Materials (Basel, Switzerland), 12(18) (2019-09-12)
Different nickel catalysts have been tested for the transformation of levulinic acid into γ-valerolactone using an easy hydrothermal method, taking advantage of the properties of the high temperature water. A metallic nickel catalyst derived from NiO synthesized by a nanocasting
Shadabul Haque et al.
Journal of controlled release : official journal of the Controlled Release Society, 307, 32-43 (2019-06-04)
The development of inhalable 'nanomedicines' based on biocompatible lipids and polymers is attracting increasing interest worldwide. Our understanding of how pulmonary inflammation impacts on lung distribution and clearance kinetics however, is limited. Similarly, there is limited information on how the
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