716715

(S)-2-[(Diphenylphosphino)methyl]pyrrolidine

• Empirical Formula (Hill Notation): C₁₇H₂₀NP
• CAS Number: 60261-46-3
• Molecular Weight: 269.32
• MDL number: MFCD16621443
• UNSPSC Code: 12352005
• PubChem Substance ID: 329763423
• NACRES: NA.22

Properties

• form: liquid
• Quality Level: 100
• optical activity: [α]22/D −24.0°, c = 0.5 in ethanol
• refractive index: n20/D 1.614
• density: 1.043 g/mL at 25 °C
• functional group: phosphine
• SMILES string: C1CN[C@@H](C1)CP(c2ccccc2)c3ccccc3
• InChI: 1S/C17H20NP/c1-3-9-16(10-4-1)19(14-15-8-7-13-18-15)17-11-5-2-6-12-17/h1-6,9-12,15,18H,7-8,13-14H2/t15-/m0/s1
• InChI key: IWRBGJKCDORZHK-HNNXBMFYSA-N

Description

Application

Catalytic ligand in:

• Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignans
• Preparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Safety Information

• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: >230.0 °F - closed cup
• flash_point_c: > 110 °C - closed cup