Skip to Content
MilliporeSigma
All Photos(1)

Key Documents

708925

Sigma-Aldrich

N-[[2-(Diphenylphosphino)phenyl]methylene]-3-methyl-L-valine sodium salt

95%

Synonym(s):

Na-tBu-DippAM

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
C25H25NNaO2P
CAS Number:
Molecular Weight:
425.44
MDL number:
UNSPSC Code:
12352116
PubChem Substance ID:
NACRES:
NA.22

assay

95%

form

powder

reaction suitability

reaction type: click chemistry

mp

199 °C (dec.)

SMILES string

[Na+].CC(C)(C)[C@H](\N=C\c1ccccc1P(c2ccccc2)c3ccccc3)C([O-])=O

InChI

1S/C25H26NO2P.Na/c1-25(2,3)23(24(27)28)26-18-19-12-10-11-17-22(19)29(20-13-6-4-7-14-20)21-15-8-5-9-16-21;/h4-18,23H,1-3H3,(H,27,28);/q;+1/p-1/b26-18+;/t23-;/m1./s1

InChI key

ZHRLPDTWOAIAKW-CCNYVGMNSA-M

Application

Used in asymmetric copper catalyzed conjugate addition

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Wencel, J. et al.
Tetrahedron Asymmetry, 19, 1804-1804 (2008)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service