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685038

Sigma-Aldrich

Tetrakisacetonitrile copper(I) triflate

Synonym(s):

Tetrakisacetonitrile copper(I) trifluoromethanesulfonate

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About This Item

Linear Formula:
Cu(NCCH3)4 · CF3SO3
Molecular Weight:
376.82
MDL number:
MFCD10566992
UNSPSC Code:
12161600
PubChem Substance ID:
329760937
NACRES:
NA.22

form

solid

reaction suitability

core: copper
reagent type: catalyst

SMILES string

[Cu+].CC#N.CC#N.CC#N.CC#N.[O-]S(=O)(=O)C(F)(F)F

InChI

1S/4C2H3N.CHF3O3S.Cu/c4*1-2-3;2-1(3,4)8(5,6)7;/h4*1H3;(H,5,6,7);/q;;;;;+1/p-1

InChI key

NOBZSXGFNYRDMS-UHFFFAOYSA-M

Application

Catalyst for greener oxidation of alcohols under aerobic conditions.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
SHBJ5810
SHBJ1633
SHBH6797
SHBG1520V
SHBF9005V

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Articles

Aerobic Alcohol Oxidation Solutions

Alcohol oxidation is one of the most frequently performed oxidation reactions in organic chemistry. The aldehyde and ketone products of alcohol oxidation are useful intermediates en route to complex molecules.

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