676578
Bis(tri-tert-butylphosphine)palladium(0)
Synonym(s):
Pd(t-Bu3P)2
About This Item
Recommended Products
form
solid
Quality Level
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
greener alternative product characteristics
Catalysis
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Greener Alternative Product
mp
258-272 °C
greener alternative category
, Aligned
storage temp.
−20°C
SMILES string
[Pd].CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C
InChI
1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;
InChI key
MXQOYLRVSVOCQT-UHFFFAOYSA-N
General description
Application
- Catalyst for Suzuki coupling on a multisubstituted sp3-carbon (eq. 1)
- Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)
- Catalyst for Negishi coupling reaction (eq. 3)
- Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)
- Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)
- Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)
On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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TPGS-750-M, a second generation surfactant, is useful for room temperature, palladium and ruthenium-catalyzed reactions in water. Reactions include the Heck reaction, Suzuki-Miyaura reaction, Sonogashira reaction, Buchwald-Hartwig amination reaction, Negishi reaction, and olefin metathesis.
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