661007

Hydroxy[-(S)-BINAP]-rhodium(I) Dimer

90%

• Empirical Formula (Hill Notation): C₈₈H₆₆O₂P₄Rh₂
• Molecular Weight: 1485.17
• MDL number: MFCD08561132
• UNSPSC Code: 12352005
• PubChem Substance ID: 24884495
• NACRES: NA.22

Properties

• assay: 90%
• form: solid
• reaction suitability: reaction type: click chemistry
• impurities: 3-5% THF; 3-5% ethanol
• SMILES string: [H]O[Rh].[H]O[Rh].c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccccc7)c8ccccc8.c9ccc(cc9)P(c%10ccccc%10)c%11ccc%12ccccc%12c%11-c%13c(ccc%14ccccc%13%14)P(c%15ccccc%15)c%16ccccc%16
• InChI: 1S/2C44H32P2.2H2O.2Rh/c2*1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;;/h2*1-32H;2*1H2;;/q;;;;2*+1/p-2
• InChI key: PWIUOLBVYNHREE-UHFFFAOYSA-L

Description

Application

Efficient and Selective Catalysts for Asymmetric Synthesis

Catalyst employed in an asymmetric 1,6-addition of arylzinc reagents to dienones leading to chiral 5-substituted enones. Also used in an asymmetric 1,4-addition of organoboron reagents to cyclic and acyclic α,β-unsaturated ketones with excellent enantioselectivity.

Safety Information

• pictograms: GHS08
• signalword: Warning
• hcodes: H351
• pcodes: P201 - P202 - P280 - P308 + P313 - P405 - P501
• Hazard Classifications: Carc. 2
• supp_hazards: EUH019
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable