594768
4-Methoxycarbonylphenylboronic acid pinacol ester
97%
Synonym(s):
4-Carbomethoxyphenylboronic acid pinacol ester, Methyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzoate
About This Item
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assay
97%
form
solid
mp
77-81 °C (lit.)
SMILES string
COC(=O)c1ccc(cc1)B2OC(C)(C)C(C)(C)O2
InChI
1S/C14H19BO4/c1-13(2)14(3,4)19-15(18-13)11-8-6-10(7-9-11)12(16)17-5/h6-9H,1-5H3
InChI key
REIZEQZILPXYKS-UHFFFAOYSA-N
Application
- In Suzuki–Miyaura cross-coupling reaction with aryl halides to form C-C bonds.
- For the synthesis of biphenyl derivatives by selective ortho C-H arylation of ketones using Rh catalyst.
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Certificates of Analysis (COA)
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Articles
The synthesis of biaryl compounds via the Suzuki–Miyaura coupling reaction has become more commonplace now that many arylboronic acids are readily available.
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