547980
Tris[N,N-bis(trimethylsilyl)amide]samarium(III)
98%
Synonym(s):
1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt, Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium
About This Item
Recommended Products
Quality Level
assay
98%
form
solid
reaction suitability
core: samarium
reagent type: catalyst
mp
93-106 °C (lit.)
SMILES string
C[Si](C)(C)N([Sm](N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)[Si](C)(C)C
InChI
1S/3C6H18NSi2.Sm/c3*1-8(2,3)7-9(4,5)6;/h3*1-6H3;/q3*-1;+3
InChI key
MUFPZLRACJKLCI-UHFFFAOYSA-N
Related Categories
Application
- Heterobimetallic samarium(III) complexes
- Binuclear lanthanide complexes
Catalyst for:
- Coordination polymerization of renewable butyrolactone-based vinyl monomers
- Intramolecular hydroamination of non-activated alkenes
- Chiral functionalization of isoxazoles
- Enantioselective hydroamination / cyclization
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Skin Corr. 1B - Water-react 2
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk_germany
WGK 3
flash_point_f
36.0 °F - closed cup
flash_point_c
2.2 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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