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522317

Sigma-Aldrich

2-Mercapto-4-methyl-5-thiazoleacetic acid

98%

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About This Item

Empirical Formula (Hill Notation):
C6H7NO2S2
CAS Number:
Molecular Weight:
189.26
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

98%

mp

207 °C (dec.) (lit.)

functional group

carboxylic acid

SMILES string

Cc1nc(S)sc1CC(O)=O

InChI

1S/C6H7NO2S2/c1-3-4(2-5(8)9)11-6(10)7-3/h2H2,1H3,(H,7,10)(H,8,9)

InChI key

KYBOCQHDFLVQIB-UHFFFAOYSA-N

General description

2-Mercapto-4-methyl-5-thiazoleacetic acid is a thiazole derivative. It participates in the preparation of dinuclear [Au-(O4NCS2)]2 and tetranuclear [Au(SSCOOH)]4 complexes.

Application

2-Mercapto-4-methyl-5-thiazoleacetic acid may be used as a capping agent in the preparation of fused spherical gold nanoparticles. It may also be used in the synthesis of eight-tin macrocyclic complex (a 40-membered macrocycle containing two distannoxane ladders).

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Dalton transactions (Cambridge, England : 2003), (12)(12), 1785-1786 (2004-09-24)
The self-assembly reaction of 2-mercapto-4-methyl-5-thiazoleacetic acid, sodium methoxide and dimethyltin dichloride in moist dichloromethane affords a novel eight-tin macrocyclic complex, which is a 40-membered macrocycle containing two distannoxane ladders.
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