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450103

Sigma-Aldrich

Yttrium(III) chloride

AnhydroBeads, −10 mesh, 99.99% trace metals basis

Synonym(s):

Yttrium trichloride

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About This Item

Linear Formula:
YCl3
CAS Number:
Molecular Weight:
195.26
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

product line

AnhydroBeads

Quality Level

assay

99.99% trace metals basis

impurities

≤150.0 ppm Trace Rare Earth Analysis

particle size

−10 mesh

mp

721 °C (lit.)

density

2.67 g/mL at 25 °C (lit.)

SMILES string

Cl[Y](Cl)Cl

InChI

1S/3ClH.Y/h3*1H;/q;;;+3/p-3

InChI key

PCMOZDDGXKIOLL-UHFFFAOYSA-K

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Application

Used to prepare yttrium alkyl alkoxide complexes under strictly anhydrous conditions.

Features and Benefits

Will react with potassium alkoxotitanates to form precursors to novel titanium-containing ceramics

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1B

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Evans, W.J. et al.
Organometallics, 15, 1351-1351 (1996)
K Marubashi et al.
Toxicology letters, 99(1), 43-51 (1998-11-04)
We investigated pulmonary clearance of yttrium (Y) and acute lung injury following intratracheal instillation (i.t.) of yttrium chloride (YCl3) in saline- or YCl3-pretreated rats (30 days before the second challenge). About 67% of the initial dose of Y remained in
N Watanabe et al.
Radiation protection dosimetry, 114(4), 509-513 (2005-05-19)
The efficacy of diethylenetriaminepentaacetate calcium trisodium (CaNa(3)DTPA) in a dose of 34.7 micromol kg(-1) as a function of its route of administration was investigated in rats with a puncture wound contaminated by (90)Y-chloride at a concentration of 2.55 MBq kg(-1).
Jérôme Hannedouche et al.
Chemical communications (Cambridge, England), (30)(30), 3552-3554 (2008-07-26)
A facile method for the preparation of highly active and enantioselective yttrium precatalysts for asymmetric hydroamination of gem-disubstituted aminoalkenes, from the combination of YCl(3) or YCl(3)(THF)(3.5) with ligand (R)- and n-BuLi is described.
Acceleration of the substitution of silanes with Grignard reagents by using either LiCl or YCl3/MeLi.
Naoki Hirone et al.
Angewandte Chemie (International ed. in English), 49(42), 7762-7764 (2010-09-08)

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