412252

(Ethoxycarbonylmethyl)triphenylphosphonium bromide

98%

• Synonym(s): (Carboxymethyl)triphenylphosphonium bromide ethyl ester, NSC 60450
• Linear Formula: CH₃CH₂OCOCH₂P(C₆H₅)₃Br
• CAS Number: 1530-45-6
• Molecular Weight: 429.29
• Beilstein/REAXYS Number: 3581273
• EC Number: 216-230-1
• MDL number: MFCD00011835
• UNSPSC Code: 12352108
• PubChem Substance ID: 24865798
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 98%
• reaction suitability: reaction type: C-C Bond Formation
• mp: 145-150 °C (dec.) (lit.)
• functional group: ester; phosphine
• SMILES string: [Br-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C22H22O2P.BrH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
• InChI key: VJVZPTPOYCJFNI-UHFFFAOYSA-M

Description

Application

Reactant for:

• Wittig olefination reactions for synthesis of tetramic acid derivatives
• Synthesis of precursors for Bergman cyclization
• Preparation of PPAR agonists derived from thalidomide-related LXR antagonists
• Synthesis of benzoxaboroles with antimalarial activity
• Michael acceptor based cysteine protease inhibitors
• Mechanistic studies of the IspH reductase protein

Safety Information

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves