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405647

Sigma-Aldrich

2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone

97%

Synonym(s):

2-(Dimethylamino)-1-(4-morpholinophenyl)-2-benzyl-1-butanone, 2-(Dimethylamino)-1-[4-(4-morpholinyl)phenyl]-2-(phenylmethyl)-1-butanone, 2-Benzyl-2-dimethylamino-1-(4-morpholinophehyl)-butane-1-one

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About This Item

Empirical Formula (Hill Notation):
C23H30N2O2
CAS Number:
Molecular Weight:
366.50
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

97%

mp

116-119 °C (lit.)

SMILES string

CCC(Cc1ccccc1)(N(C)C)C(=O)c2ccc(cc2)N3CCOCC3

InChI

1S/C23H30N2O2/c1-4-23(24(2)3,18-19-8-6-5-7-9-19)22(26)20-10-12-21(13-11-20)25-14-16-27-17-15-25/h5-13H,4,14-18H2,1-3H3

InChI key

UHFFVFAKEGKNAQ-UHFFFAOYSA-N

General description

2-Benzyl-2-(dimethylamino)-4′-morpholinobutyrophenone (DBMP) is a photoinitiator that acts at near UV and visible range. It can be incorporated into the polymeric matrix, which upon UV irradiation forms radicals by radical chain polymerization.

Application

DBMP can be used as a dopant to dope silicone elastomer for the formation of 3D biocompatible scaffolds. It can also be used in two photon polymerization for the micro-fabrication of 3D hydrogels for potential biomedical and tissue engineering applications.

pictograms

Health hazardEnvironment

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

235.4 °F

flash_point_c

113 °C

ppe

Eyeshields, Gloves


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Yahya Bougdid et al.
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Voxels, the 3D equivalent of 2D pixels, are obtained by individual point exposures in 3D laser nanoprinting, and are the building blocks of laser printed 3D micro/nano-structures, and their optimization is important in determining the resolution of printed 3D objects.
Photoinduced free radical promoted copper (I)-catalyzed click chemistry for macromolecular syntheses
Tasdelen MA, et al.
Macromolecules, 45(1), 56-61 (2011)
A water soluble initiator prepared through host-guest chemical interaction for microfabrication of 3D hydrogels via two-photon polymerization
Xing J, et al.
Journal of materials chemistry. B, 2(27), 4318-4323 (2014)
Laser interaction in sol-gel based materials-3-D lithography for photonic applications
Houbertz R
Applied Surface Science, 247(1-4), 504-512 (2005)
Three-dimensional laser micro-sculpturing of silicone: towards bio-compatible scaffolds
Rekstyt? S, et al.
Optics Express, 21(14), 17028-17041 (2013)

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