389560
Phenylphosphonic dichloride
technical grade, 90%
Synonym(s):
Benzenephosphonic dichloride, Benzenephosphonyl chloride, Phenyldichlorophosphine oxide, Phenylphosphonyl dichloride, Phenylphosphoryl dichloride, P,P-Dichlorophenylphosphine oxide
About This Item
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grade
technical grade
Quality Level
assay
90%
form
liquid
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
refractive index
n20/D 1.559 (lit.)
bp
258 °C (lit.)
mp
3 °C (lit.)
density
1.375 g/mL at 25 °C (lit.)
SMILES string
ClP(Cl)(=O)c1ccccc1
InChI
1S/C6H5Cl2OP/c7-10(8,9)6-4-2-1-3-5-6/h1-5H
InChI key
IBDMRHDXAQZJAP-UHFFFAOYSA-N
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Application
It can be used:
- In the synthesis of PBPP (3,9-diphenyl-3,9-dioxa-2,4,8,10-tetraoxa-3,9-diphosphaspiro-5,5-undecane), another organo-phosphorus flame retardant.
- As a reactant in the synthesis of perfluoroalkyl(phenyl)phosphinic acids from perfluoroalkyl Grignard reagents.
- As a starting material for the synthesis of benzoxazine monomer containing phenylphosphine oxide which can be polymerized via ring-opening polymerization.
- As a chlorinating agent for the conversion of thienopyrimidinedione into 4,6-dichlorothienopyrimidine.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
Storage Class
8A - Combustible corrosive hazardous materials
wgk_germany
WGK 3
flash_point_f
399.2 °F
flash_point_c
204 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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