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388211

Sigma-Aldrich

Perfluorooctanes

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About This Item

MDL number:
UNSPSC Code:
12352100
NACRES:
NA.22

form

liquid

Quality Level

refractive index

n20/D 1.3 (lit.)

bp

103-105 °C (lit.)

density

1.766 g/mL at 25 °C (lit.)

Application

Perfluorooctanes can be used as a fluorous solvent for aerobic oxidation of alcohols to carbonyl compounds in fluorous biphasic systems. It can also be employed in the synthesis of perfluoroalkyl-substituted bis(oxazolines).

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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Cobalt (II) perfluorooctane sulfonate catalyzed highly efficient aerobic oxidation of alcohols in fluorous biphasic systems.
Yi WB and Cai C
Australian Journal of Chemistry, 59(5), 349-353 (2006)
Synthesis of Perfluoroalkyl-Substituted Bis (oxazolines) as Ligands for Catalytic Enantioselective Reactions.
Annunziata R, et al.
European Journal of Organic Chemistry, 2003(7), 1191-1197 (2003)

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