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370959

Sigma-Aldrich

Lignin, alkali

Synonym(s):

Lignin, kraft

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About This Item

CAS Number:
MDL number:
UNSPSC Code:
12162002
NACRES:
NA.23

description

surface tension 43 mN/m (1% aqueous)

Quality Level

form

powder

impurities

5% moisture

loss

13.4 wt. % loss on heating, @ 316°C
3.3 wt. % loss on heating, @ 149°C
5.7 wt. % loss on heating, @ 204°C
8.5 wt. % loss on heating, @ 260°C

pH

6.5 (25 °C, 5%, aqueous solution)

transition temp

sintering point 188 °C

solubility

NaOH: 0.05% (warm 5% aquesous)
MEK: partially soluble
benzene: insoluble
dioxane: soluble
ethylene glycol: soluble
hexane: insoluble
methanol: partially soluble

density

1.3 g/mL at 25 °C

bulk density

23 lb/cu.ft (loose)
32 lb/cu.ft (packed)

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General description

Lignin, alkali is a complex, three dimensional polymer that is also known as kraft lignin that has undergone hydrolytic degradation. It is one of the major components of lignocellulosic materials. Lignin is a major product for second generation bioethanol production and is an impurity in the separation of cellulose from wood.

Application

Lignin, alkali can be used as a surface treatment agent for composites of natural fibers with petroleum based resins. It can be used as a biosorbent for potential applications in removing toxic metal ions from wastewater.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)


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Adriana L Romero-Olivares et al.
PloS one, 12(6), e0179674-e0179674 (2017-06-18)
Over the long term, soil carbon (C) storage is partly determined by decomposition rate of carbon that is slow to decompose (i.e., recalcitrant C). According to thermodynamic theory, decomposition rates of recalcitrant C might differ from those of non-recalcitrant C
Aiguo Wang et al.
Bioresource technology, 268, 505-513 (2018-08-17)
Maximizing the production of aromatic hydrocarbons from lignin conversion by coupling methane activation without solvent was investigated over Zn-Ga modified zeolite catalyst. The co-loading of Zn and Ga greatly improves lignin conversion, arene yield along with BTEX (i.e., benzene, toluene
Shangxian Xie et al.
Advanced science (Weinheim, Baden-Wurttemberg, Germany), 6(13), 1801980-1801980 (2019-08-06)
Bacterial protein secretion represents a significant challenge in biotechnology, which is essential for the cost-effective production of therapeutics, enzymes, and other functional proteins. Here, it is demonstrated that proteomics-guided engineering of transcription, translation, secretion, and folding of ligninolytic laccase balances
Yong Sik Kim et al.
Biomacromolecules, 11(4), 981-988 (2010-03-02)
Copolymerization of N-isopropylacrylamide (NIPAM) with technical hardwood kraft lignin (HWKL) was achieved by atom transfer radical polymerization (ATRP) using a selectively modified lignin-based macroinitiator. The degree of polymerization (DP) of polyNIPAM graft side chains was affected by varying the ratio
Héctor Rodríguez et al.
Physical chemistry chemical physics : PCCP, 11(46), 10916-10922 (2009-11-20)
We have found that 1-alkyl-3-methylimidazolium chloride ionic liquids (ILs) can form immiscible liquid mixtures with some polyethylene glycols (PEGs). Binary mixtures of 1-ethyl-3-methylimidazolium chloride with PEG of molecular weight 1500, 2000, or 3400 g mol(-1), or of 1-butyl-3-methylimidazolium chloride with

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