341630

Chloro(pyridine)bis(dimethylglyoximato)cobalt(III)

• Synonym(s): Chloro(pyridine)cobaloxime(III), NSC 175756
• Empirical Formula (Hill Notation): C₁₃H₁₉ClCoN₅O₄
• CAS Number: 23295-32-1
• Molecular Weight: 403.71
• MDL number: MFCD00075236
• UNSPSC Code: 12352300
• PubChem Substance ID: 24860975
• NACRES: NA.22

Properties

• Quality Level: 100
• reaction suitability: core: cobalt; reaction type: Photocatalysis; reagent type: catalyst
• mp: 235 °C (dec.) (lit.)
• SMILES string: c1ccncc1.CC(=N\O)\C(C)=N/O[Co](Cl)O\N=C(C)/C(C)=N\O
• InChI: 1S/C5H5N.2C4H8N2O2.ClH.Co/c1-2-4-6-5-3-1;2*1-3(5-7)4(2)6-8;;/h1-5H;2*7-8H,1-2H3;1H;/q;;;;+3/p-3/b;2*5-3-,6-4-;;
• InChI key: CKWAWSVVCRVWHW-PCJYWUFNSA-K

Description

Application

Catalyst for:

• Photocatalytic H₂ generation from water under visible light
• Doetz benzannulation reaction
• Proton electroreduction reactions
• Radical heterocyclization reactions
• Preparation of Mannich base analogues

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315 - H319 - H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves