326348

Iron(III) perchlorate hydrate

crystalline, low chloride

• Synonym(s): Perchloric acid iron(III) salt hydrate
• Linear Formula: Fe(ClO₄)₃ · xH₂O
• CAS Number: 15201-61-3
• Molecular Weight: 354.20 (anhydrous basis)
• EC Number: 236-908-0
• MDL number: MFCD00149705
• UNSPSC Code: 12352000
• PubChem Substance ID: 24859580
• NACRES: NA.22

Properties

• form: crystalline
• reaction suitability: reagent type: oxidant
• impurities: <0.005% chloride
• color: pale violet
• SMILES string: [Fe+3].[H]O[H].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O
• InChI: 1S/3ClHO4.Fe.H2O/c3*2-1(3,4)5;;/h3*(H,2,3,4,5);;1H2/q;;;+3;/p-3
• InChI key: PFPIMAZLJXJVAN-UHFFFAOYSA-K

Description

Application

Catalyst for synthesis of:

• Fullerene-fused lactones
• α-Carbonyl furans via one-pot cyclization
• Fullerodioxolanes via heterocyclization
• Dialylated indoles via double alkylation
• Aryl esters via oxidative esterification

Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution

Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization

Useful starting material for the synthesis of a tris-salicylate Fe(III) complex having bidentate chelating units which allow two coordination modes.

Safety Information

• pictograms: GHS03,GHS07
• signalword: Danger
• hcodes: H272,H315,H319,H335
• pcodes: P210 - P220 - P261 - P264 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Ox. Sol. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 5.1A - Strongly oxidizing hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves, type P3 (EN 143) respirator cartridges