324876

N-(Triphenylphosphoranylidene)aniline

97%

• Synonym(s): Anilidenetriphenylphosphorane, Tetraphenylphosphine imide
• Linear Formula: (C₆H₅)₃P=NC₆H₅
• CAS Number: 2325-27-1
• Molecular Weight: 353.40
• EC Number: 219-039-1
• MDL number: MFCD00003044
• UNSPSC Code: 12352100
• PubChem Substance ID: 24859473
• NACRES: NA.22

Properties

• assay: 97%
• impurities: <0.5% denatured ethanol
• solubility: chloroform: soluble 25 mg/mL, clear to slightly hazy (colorless to brown)
• SMILES string: c1ccc(cc1)N=P(c2ccccc2)(c3ccccc3)c4ccccc4
• InChI: 1S/C24H20NP/c1-5-13-21(14-6-1)25-26(22-15-7-2-8-16-22,23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H
• InChI key: PTLOPIHJOPWUNN-UHFFFAOYSA-N

Description

General description

N-(Triphenylphosphoranylidene)aniline was reported as a new electrolyte additive for high performance lithium cobalt oxide (LiCoO₂) electrodes during high voltage operations in lithium ion batteries.

Application

The Staudinger Ligation: A High-Yield, Chemoselective, and Mild Synthetic Method

Intermediate for the preparation of isocyanates and isothiocyanates.

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315 - H319 - H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• ppe: dust mask type N95 (US), Eyeshields, Gloves